p-TRIFLUOROMETHYLTETRAFLUOROPHENYLTRIETHOXYSILANE

Product Code: SIT8345.0
CAS No: 561069-04-3
SDS Sheets: EU | US
Pack Size
Quantity
Price
 
5 g
$141.00
25 g
$561.00

Product data and descriptions listed are typical values, not intended to be used as specification.

  • HMIS

    3-2-1-X
  • Molecular Formula

    C13H15F7O3Si
  • Molecular Weight (g/mol)

    380.33
  • Density (g/mL)

    1.29
  • Refractive Index @ 20˚C

    1.4068

Additional Properties

  • Hydrolytic Sensitivity

    7: reacts slowly with moisture/water
  • Safety

  • Packaging Under

    Nitrogen
  • Arylsilane Cross-Coupling Agent

    The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.

    p-Trifluoromethyltetrafluorophenyltriethoxysilane; p-Triethoxysilylperfluorotoluene

  • Forms H-free resins
  • Example of fluorinated arylsilane for cross-coupling
  • Extensive review of silicon based cross-coupling agents: Denmark, S. E. et al. "Organic Reactions, Volume 75" Denmark, S. E. ed., John Wiley and Sons, 233, 2011
  • Silicon Chemistry, Articles

    Silicon-Based Formation of Carbon-Carbon Bonds – Larson

    Hatanaka and Hiyama first reported the palladium-catalyzed, fluoride-promoted reaction of aryl, alkenyl, allyl, and ethynyltrimethylsilanes with aryl, vinil and allyl halides to form the respective cross-coupled products