- Synonyms 2-(TRIMETHYLSILYL)VINYLBROMIDE
- HMIS 2-3-1-X
- Molecular Formula C5H11BrSi
- Molecular Weight (g/mol) 179.13
- Purity (%) 97%
- TSCA No
- Boiling Point (˚C/mmHg) 50-1° / 52
- Density (g/mL) 1.167
- Flash Point (˚C) 29 °C
- Refractive Index @ 20˚C 1.467
Potential for cross-coupling protocols to yield ?-substituted vinylsilanes.1
Starting point for substituted vinyl silanes
1. Larson, G. L. “Silicon-Based Cross-Coupling Reagents” Gelest, Inc. 2011.
F&F: Vol. 11, p 82.
Alkenylsilane Cross-Coupling Agent
The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.
Silicon Chemistry, Articles
Hatanaka and Hiyama first reported the palladium-catalyzed, fluoride-promoted reaction of aryl, alkenyl, allyl, and ethynyltrimethylsilanes with aryl, vinil and allyl halides to form the respective cross-coupled products