VINYLDIMETHYLCHLOROSILANE

Product Code: SIV9070.0
CAS No: 1719-58-0
SDS Sheets: EU | US
COMMERCIAL
1719-58-0
Pack Size
Quantity
Price
 
25 g
$39.00
250 g
$270.00
750 g
$544.00
16 kg
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150 kg
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Product data and descriptions listed are typical values, not intended to be used as specification.

  • Einecs Number

    217-007-1
  • HMIS

    3-4-1-X
  • Molecular Formula

    C4H9ClSi
  • Molecular Weight (g/mol)

    120.65
  • TSCA

    Yes
  • Boiling Point (˚C/mmHg)

    82-3°
  • Density (g/mL)

    0.884
  • Flash Point (˚C)

    -5°C (23°F)
  • Refractive Index @ 20˚C

    1.4137

Additional Properties

  • Hydrolytic Sensitivity

    8: reacts rapidly with moisture, water, protic solvents
  • Application

    Review of synthetic utility.1
    Used in synthesis of highly substituted unsaturated alcohols.2
    Reductively cross-couples with allyl alcohols to form butenols after oxidation.3
    Used to silylate unsaturated alcohols, which can be RCM-cyclized to a vinylsilyl ether, which in turn can be subjected to a silicon-based cross-coupling.4

    Reference

    1. Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, Fuchs, P. L. Ed., John Wiley and Sons, Ltd., 2011, p. 157-161.
    2. Denmark, S. E.; Lang, S. M. Org. Lett. 2001, 3, 1749.
    3. Belardi J. K.; Micalizio, G. C. J. Am. Chem. Soc. 2008, 130, 16870.
    4. Denmark, S. E.; Yang, S.-M. Org. Lett. 2003, 3, 1749.

    Safety

  • Packaging Under

    Nitrogen