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Boiling Point: 160-5° / 3
EINECS Number: 212-333-0
Melting Point: 42-4°
Molecular Weight: 260.41
Flashpoint: >200°C (>392°F)
HMIS Key: 2-1-1-X
Hydrolytic Sensitivity: 3: reacts with aqueous base
Refractive Index: 1.6160
Application: Review of synthetic utility.1
In presence of di-t-butylperoxide reduces esters to hydrocarbons.2
Undergoes dehydrogenative coupling with alcohols.2
Reference: 1. Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, Fuchs, P. L. Ed., John Wiley and Sons, Ltd., 2011, p. 733-739.
2. Sano, H. et al. Chem. Lett. 1986, 77.
3. Yamanoi, Y. J. Org. Chem. 2005, 70, 9607.
Fieser: F&F: Vol. 12, p 209; Vol. 13, p 334.