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Boiling Point: 53-5° / 11
EINECS Number: 220-844-5
Molecular Weight: 118.25
Specific Gravity: 0.945
Flashpoint: 56°C (133°F)
HMIS Key: 2-3-0-X
Hydrolytic Sensitivity: 4: no reaction with water under neutral conditions
Refractive Index: 1.436
Application: Review of synthetic utility.1
Serves as an alcohol equivalent in reaction with aryl iodides.2
Can provide protection for the anomeric center of carbohydrates.3
Reference: 1. Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, Fuchs, P. L. Ed., John Wiley and Sons, Ltd., 2011, p. 622-627.
2. >Dibakar, M. et al. Tetrahedron Lett. 2011, 41, 5338.
3. Sowell, C. G. et al. Tetrahedron Lett. 1996, 37, 609.
Fieser: F&F: Vol. 8, p 510.
Additional Properties: Eliminates ethylene in presence of acid or base