2916-68-9

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2-(TRIMETHYLSILYL)ETHANOL

Product Code: SIT8589.2

Cas No: 2916-68-9

R&D quantities:

10gm
$130.00
2kg
$2,936.00
50gm
$517.00

Boiling Point: 53-5° / 11

EINECS Number: 220-844-5

Molecular Weight: 118.25

Specific Gravity: 0.945

Flashpoint: 56°C (133°F)

HMIS Key: 2-3-0-X

Hydrolytic Sensitivity: 4: no reaction with water under neutral conditions

Formula: C5H14OSi

Refractive Index: 1.436

Application: Review of synthetic utility.1
Serves as an alcohol equivalent in reaction with aryl iodides.2
Can provide protection for the anomeric center of carbohydrates.3

Reference: 1. Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, Fuchs, P. L. Ed., John Wiley and Sons, Ltd., 2011, p. 622-627.
2. Dibakar, M. et al. Tetrahedron Lett. 2011, 41, 5338.
3. Sowell, C. G. et al. Tetrahedron Lett. 1996, 37, 609.

Fieser: F&F: Vol. 8, p 510.

Additional Properties: Eliminates ethylene in presence of acid or base