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TRIMETHYLSILANE
Boiling Point: 6.7°
EINECS Number: 213-603-0
Melting Point: -135.9°
Molecular Weight: 74.20
Alternative Name: 3MS
Specific Gravity: 0.638
HMIS Key: 2-4-1-X
Hydrolytic Sensitivity: 3: reacts with aqueous base
Formula: C3H10Si
TSCA: TSCA
Application: Employed in plasma treatment of surfaces.1
Treatment of titanium alloys and stainless steel surfaces inhibits biofilm formation.2
Reference: 1. Hendricks, N. et al. Semiconductor Int'l. 2000, 23, 95.
2. Ma, Y. et al. Antimicrob. Agents Chemother. 2012, 56, 5923.
Fieser: F&F: Vol. 1, p 1235; Vol. 2, p 441; Vol. 13, p 101; Vol. 16, p 292.
Additional Properties: 320Dipole moment: 0.52 debye?Hcomb: -766 kcal/moleCritical temperature: 158.85°C?Hform: -39 kcal/moleCritical pressure: 31.48 atm?Hvap: 5.8 kcal/moleForms trimethylsilylalkanes from olefins w/Pt catalystVapor pressure, 25°: 1,218 mm
Silicone
Silanes
Key Organosilane Reductions – Larson
The Synthesis of Gliflozins – Larson
Organosilane Reductions with Polymethylhydrosiloxanes – Larson
Tetramethyldisiloxane: A Practical Organosilane Reducing Agent – Larson
Understanding ALD MLD and SAMs as they enter the fab – Arkles, Goff, & Kaloyeros