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Product Code: SID3535.0

Cas No: 2227-29-4

R&D quantities:

25 g
5 g
750 g

Boiling Point: 137°

Molecular Weight: 150.72

Specific Gravity: 0.872

Flashpoint: 22°C (72°F)

HMIS Key: 3-4-1-X

Hydrolytic Sensitivity: 8: reacts rapidly with moisture, water, protic solvents

Formula: C6H15ClSi

Refractive Index: 1.4278


Application: Review of synthetic utility.1
Reduces ?-hydroxyketones stereoselectively.2
Used in the tethered reactions of unsaturated alcohols.3
Used in the silicon-based cross-coupling of vinyl ethers with aryl iodides.4

Reference: 1. Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, Fuchs, P. L. Ed., John Wiley and Sons, Ltd., 2011, p. 151-156.
2. Anwar, S. et al. Chem. Comm. 1986, 831.
3. Robertson, J. et al. Tetrahedron Lett. 1998, 39, 669.
4. Evans, P. A.; Baum, E. W. J. Am. Chem. Soc. 2004, 126, 11150.