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EINECS Number: 229-675-1
Alternative Name: 1-(TRIMETHYLSILOXY)CYCLOHEXENE
Specific Gravity: 0.885
Flashpoint: 51°C (124°F)
HMIS Key: 3-2-1-X
Hydrolytic Sensitivity: 7: reacts slowly with moisture/water
Refractive Index: 1.447
Application: Reacts with ethylene oxide to give ?-hydroxy ketones.1
Reacts with aldehydes, acetals, and enones w/o Lewis acid catalysis in the presence of hexafluoro-2-propanol.2
Hydroboration/oxidation leads to trans-1,2-diols.3
Hydroboration/elimination converts silyl enol ethers to olefins.4
Reference: 1. Lalic, G. et al. Tetrahedron Lett. 2000, 41, 763.
2. Ratnikov, M. O. et al. Angew. Chem., Int. Ed. Engl.2008, 47, 9739.
3. >Larson, G. L. et al. J. Organomet. Chem. 1974, 76, 9.
4. Larson, G. L. et al. Tetrahedron Lett. 1975, 4005.