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(CYCLOHEXENYLOXY)TRIMETHYLSILANE
Boiling Point: 67-8° / 16
EINECS Number: 229-675-1
Molecular Weight: 170.33
Alternative Name: 1-(TRIMETHYLSILOXY)CYCLOHEXENE
Specific Gravity: 0.885
Flashpoint: 51°C (124°F)
HMIS Key: 3-2-1-X
Hydrolytic Sensitivity: 7: reacts slowly with moisture/water
Formula: C9H18OSi
Refractive Index: 1.447
TSCA: TSCA
Application: Reacts with ethylene oxide to give ?-hydroxy ketones.1
Reacts with aldehydes, acetals, and enones w/o Lewis acid catalysis in the presence of hexafluoro-2-propanol.2
Hydroboration/oxidation leads to trans-1,2-diols.3
Hydroboration/elimination converts silyl enol ethers to olefins.4
Reference: 1. Lalic, G. et al. Tetrahedron Lett. 2000, 41, 763.
2. Ratnikov, M. O. et al. Angew. Chem., Int. Ed. Engl.2008, 47, 9739.
3. Larson, G. L. et al. J. Organomet. Chem. 1974, 76, 9.
4. Larson, G. L. et al. Tetrahedron Lett. 1975, 4005.
Silanes