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- Einecs Number 229-675-1
- Synonyms 1-(TRIMETHYLSILOXY)CYCLOHEXENE
- HMIS 3-2-1-X
- Molecular Formula C9H18OSi
- Molecular Weight (g/mol) 170.33
- TSCA Yes
- Boiling Point (˚C/mmHg) 67-8° / 16
- Density (g/mL) 0.885
- Flash Point (˚C) 51°C (124°F)
- Refractive Index @ 20˚C 1.447
Additional Properties
Application
Reacts with ethylene oxide to give ?-hydroxy ketones.1
Reacts with aldehydes, acetals, and enones w/o Lewis acid catalysis in the presence of hexafluoro-2-propanol.2
Hydroboration/oxidation leads to trans-1,2-diols.3
Hydroboration/elimination converts silyl enol ethers to olefins.4
Reference
1. Lalic, G. et al. Tetrahedron Lett. 2000, 41, 763.
2. Ratnikov, M. O. et al. Angew. Chem., Int. Ed. Engl.2008, 47, 9739.
3. Larson, G. L. et al. J. Organomet. Chem. 1974, 76, 9.
4. Larson, G. L. et al. Tetrahedron Lett. 1975, 4005.
Safety
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