ALUMINUM ISOPROPOXIDE

Product Code: AKA070
CAS No: 555-31-7
SDS Sheets: EU | US
COMMERCIAL
555-31-7
Pack Size
Quantity
Price
 
100 g
$21.00
1 kg
$76.00
10 kg
$380.00
140 kg
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Product data and descriptions listed are typical values, not intended to be used as specification.

  • Einecs Number

    209-090-8
  • HMIS

    2-2-1-X
  • Molecular Formula

    C9H21AlO3
  • Molecular Weight (g/mol)

    204.25
  • TSCA

    Yes
  • Delta H Vaporization (kJ/mol)

    19.4 kcal/mole
  • Boiling Point (˚C/mmHg)

    135-138/10
  • Density (g/mL)

    1.035
  • Melting Point (˚C)

    118.5°

Additional Properties

  • Hydrolytic Sensitivity

    8: reacts rapidly with moisture, water, protic solvents
  • Application

    Reagent for the reduction of carbonyls to alcohols (Meerwein-Pondorf).1,2
    Forms refractory binder with Si(OEt)4.3
    Reacts with higher glycols in non-hydrolytic method to yield ceramics.4
    Forms highly organized mesoporous silica with EO-PO-EO structure directing agent.5

    Fieser

    2. F&F: Vol. 1, p 35; Vol. 3, p 10; Vol. 4, p 15; Vol. 5, p 14; Vol. 6, p 19; Vol. 8, p 15; Vol. 9, p 14; Vol. 11, p 29.

    Reference

    1. Org. Synth. 1944, Coll. Vol. 2, 178; 1955, Coll. Vol. 3, 207; 1963, Coll. Vol. 4, 192.
    3. Emblem, H. et al. PCT Int'l App. 8801991, 1988; Chem. Abstr. 109, 26743p.
    4. Inoue, M. et al. J. Mater. Sci. 1992, 11, 269.
    5. Dacquin, J. et al. J. Am. Chem. Soc. 2009, 131, 12896.

    Safety

  • Hazard Info

    oral rat, LD50: 11,300 mg/kg
  • Packaging Under

    Nitrogen