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EINECS Number: 209-090-8
Specific Gravity: 1.035
HMIS Key: 2-2-1-X
Hydrolytic Sensitivity: 8: reacts rapidly with moisture, water, protic solvents
Application: Reagent for the reduction of carbonyls to alcohols (Meerwein-Pondorf).1,2
Forms refractory binder with Si(OEt)4.3
Reacts with higher glycols in non-hydrolytic method to yield ceramics.4
Forms highly organized mesoporous silica with EO-PO-EO structure directing agent.5
Reference: 1. Org. Synth. 1944, Coll. Vol. 2, 178; 1955, Coll. Vol. 3, 207; 1963, Coll. Vol. 4, 192.
3. Emblem, H. et al. PCT Int'l App. 8801991, 1988; Chem. Abstr. 109, 26743p.
4. Inoue, M. et al. J. Mater. Sci. 1992, 11, 269.
5. Dacquin, J. et al. J. Am. Chem. Soc. 2009, 131, 12896.
Fieser: 2. F&F: Vol. 1, p 35; Vol. 3, p 10; Vol. 4, p 15; Vol. 5, p 14; Vol. 6, p 19; Vol. 8, p 15; Vol. 9, p 14; Vol. 11, p 29.
Additional Properties: 3?Hvap: 19.4 kcal/moleHot Isopropanol, Toluene