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ALUMINUM s-BUTOXIDE
Product data and descriptions listed are typical values, not intended to be used as specification.
EINECS Number: 218-871-2
Alternative Name: ALUMINUM TRI-sec-BUTOXIDE
Specific Gravity: 0.9671
Flashpoint: 27
HMIS Key: 2-3-1-X
Hydrolytic Sensitivity: 8: reacts rapidly with moisture, water, protic solvents
Formula: C12H27AlO3
TSCA: TSCA
Refractive Index: 1.438
Application: Employed in preparation of alumina sols and ceramers1,2 and cordierties.3
Primer for adhesives on mild steel.4
Used to make specialty, solid and recyclable catalyst systems for oxidations,5 azide cycloadditions,6 and oxidation and amination of hydroquinones.8
Reference: 1. Wang, B. et al. Polym. Prepr. 1989, 30, 146.
2. Aryal, A. et al. "Better Ceramics Through Chemistry III" Brinker, Ed. MRS, 1989, p239.
3. Okuyama, M. J. Mater. Res. 1992, 7, 280.
4. Menon, B. et al. in "Silanes & Other Coupling Agents" Mittal, K. Ed. VSP, 1993, p569.
5. Kim, W.-H.; Park, I. S.; Park, J. Org. Lett. 2006, 8, 2543.
6. Park, I. S. et al. Org. Lett. 2008, 10, 497.
7. Kim, S.; Kim, D.; Park, J. Adv. Synth. Catal. 2009, 351, 2573.
Additional Properties: 2.4?Hvap: 21.5 kcal/mole
Metal-Organics
Bulk Metal-Organics and Silanes: Pharmaceutical & Organic Synthesis