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ALUMINUM s-BUTOXIDE
Boiling Point: 200-6° / 30
EINECS Number: 218-871-2
Molecular Weight: 246.32
Alternative Name: ALUMINUM TRI-sec-BUTOXIDE
Specific Gravity: 0.9671
Flashpoint: 27°C (81°F)
HMIS Key: 2-3-1-X
Hydrolytic Sensitivity: 8: reacts rapidly with moisture, water, protic solvents
Formula: C12H27AlO3
Refractive Index: 1.438
TSCA: TSCA
Application: Employed in preparation of alumina sols and ceramers1,2 and cordierties.3
Primer for adhesives on mild steel.4
Used to make specialty, solid and recyclable catalyst systems for oxidations,5 azide cycloadditions,6 and oxidation and amination of hydroquinones.8
Reference: 1. Wang, B. et al. Polym. Prepr. 1989, 30, 146.
2. Aryal, A. et al. "Better Ceramics Through Chemistry III" Brinker, Ed. MRS, 1989, p239.
3. Okuyama, M. J. Mater. Res. 1992, 7, 280.
4. Menon, B. et al. in "Silanes & Other Coupling Agents" Mittal, K. Ed. VSP, 1993, p569.
5. Kim, W.-H.; Park, I. S.; Park, J. Org. Lett. 2006, 8, 2543.
6. Park, I. S. et al. Org. Lett. 2008, 10, 497.
7. Kim, S.; Kim, D.; Park, J. Adv. Synth. Catal. 2009, 351, 2573.
Additional Properties: Molecular complexity: 2.4?Hvap: 21.5 kcal/mole
Metal-Organics