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Boiling Point: 160-1°
EINECS Number: 201-081-7
Molecular Weight: 190.31
Specific Gravity: 0.903
Flashpoint: 44°C (111°F)
HMIS Key: 1-2-1-X
Hydrolytic Sensitivity: 7: reacts slowly with moisture/water
Refractive Index: 1.3960
Application: Reacts with enamines to give (E)-?-silylenamines, which cross-couple w/ aryl iodides to give ?-aryl enamines.1
Extensive review on the use in silicon-based cross-coupling reactions.2
Reference: 1. Marciniec, B. et al. J. Org. Chem. 2005, 70, 8550.
2. Denmark, S. E. et al. Organic Reactions, Vol. 75, Denmark, S. E. ed., John Wiley and Sons, 233, 2011.
Additional Properties: 268Dipole moment: 1.69 debye?c of treated glass surface: 25 mN/mSpecific wetting surface area: 412 m2/g?Hform: -463.5 kcal/mole?Hvap: 6.8 kcal/moleSpecific heat: 0.25 cal/g/°Relative hydrolysis rate versus SIV9220.0, vinyltrimethoxysilane; 0.05Vapor pressure, 20°: 5 mm