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EINECS Number: 211-670-0
Specific Gravity: 1.36
Flashpoint: 168°C (334°F)
HMIS Key: 3-1-1-X
Hydrolytic Sensitivity: TSCA
Refractive Index: 1.499
Application: Catalyzes condensations of cyclic ketones with amines to form imines.1
Blocking agent for diols.2
Effective phase transfer catalyst.3
Forms high M.W. polystannanes by Wurtz coupling.4
Catalyzes phenylsilane reductive aminations of aldehydes and ketones.5
Reference: 1. Stetin, C. et al. Synth. Commun. 1982, 12, 495.
2. Izquierdo, C. Chem. Abstr. 112, 21205s; An. Quim., Ser. 6 1988, 84, 340.
3. Armstrong, D. et al. Tetrahedron Lett. 1979, 47, 4525.
4. Devylder, N. et al. J. Chem. Soc., Chem. Commun. 1996, 711.
5. Apodaca, R.; Xiao, W. Org Lett. 2001, 3, 1745.
Additional Properties: Soluble: hexane, ether, THFDipole moment: 4.38 debyeHexane, Ether, THF