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VINYLTRIMETHOXYSILANE

Name: VINYLTRIMETHOXYSILANE
SKU: SIV9220.0
Availability: InStock

Product Code: SIV9220.0

Cas No: 2768-02-7

R&D quantities:

25 g

$15.00

2 kg

$114.00

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Boiling Point: 123°

EINECS Number: 220-449-8

Molecular Weight: 148.23

Specific Gravity: 0.970

Flashpoint: 28°C (82°F)

HMIS Key: 3-3-1-X

Hydrolytic Sensitivity: 7: reacts slowly with moisture/water

Formula: C₅H₁₂O₃Si

Refractive Index: 1.3930

TSCA: TSCA

Application: Employed in two-stage^{1 and one-stage^{2 graft polymerization/crosslinking for PE
Copolymerizes with ethylene to form moisture crosslinkable polymers.³
Converts arylselenyl bromides to arylvinylselenides.⁴
Reacts with anhydrides to transfer both vinyl and methoxy and thus form the mixed diester.⁵
Cross-couples w/ ?-bromo esters to give ?-vinyl esters in high ee.⁶}}

Reference: 1. Scott, H. U.S. Patent 3,646,155, 1972.
2. Swarbrick, P. et al. U.S. Patent 4,117,195, 1978.
3. Isaka, T. et al. U.S. Patent 4,413,066, 1983.
4. Bhadra, S. et al. J. Org. Chem. 2010, 75, 4864.
5. Luo, F. et al. J. Org. Chem. 2010, 75, 5379.
6. Strotman, N. A.; Sommer, S.; Fu, G. C. Angew. Chem., Int. Ed. Engl. 2007, 46, 3556.