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Boiling Point: 123°
EINECS Number: 220-449-8
Molecular Weight: 148.23
Specific Gravity: 0.970
Flashpoint: 28°C (82°F)
HMIS Key: 3-3-1-X
Hydrolytic Sensitivity: 7: reacts slowly with moisture/water
Refractive Index: 1.3930
Application: Employed in two-stage1 and one-stage2 graft polymerization/crosslinking for PE
Copolymerizes with ethylene to form moisture crosslinkable polymers.3
Converts arylselenyl bromides to arylvinylselenides.4
Reacts with anhydrides to transfer both vinyl and methoxy and thus form the mixed diester.5
Cross-couples w/ ?-bromo esters to give ?-vinyl esters in high ee.6
Reference: 1. Scott, H. U.S. Patent 3,646,155, 1972.
2. Swarbrick, P. et al. U.S. Patent 4,117,195, 1978.
3. Isaka, T. et al. U.S. Patent 4,413,066, 1983.
4. >Bhadra, S. et al. J. Org. Chem. 2010, 75, 4864.
5. >Luo, F. et al. J. Org. Chem. 2010, 75, 5379.
6. Strotman, N. A.; Sommer, S.; Fu, G. C. Angew. Chem., Int. Ed. Engl. 2007, 46, 3556.
Additional Properties: 235Specific wetting surface area: 528 m2/gVapor pressure, 20°: 9 mm