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Product Code: SIV9112.0

Cas No: 78-08-0

R&D quantities:

25 g
2 kg

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Boiling Point: 160-1°

EINECS Number: 201-081-7

Molecular Weight: 190.31

Specific Gravity: 0.903

Flashpoint: 44°C (111°F)

HMIS Key: 1-2-1-X

Hydrolytic Sensitivity: 7: reacts slowly with moisture/water

Formula: C8H18O3Si

Refractive Index: 1.3960


Application: Reacts with enamines to give (E)-?-silylenamines, which cross-couple w/ aryl iodides to give ?-aryl enamines.1
Extensive review on the use in silicon-based cross-coupling reactions.2

Reference: 1. Marciniec, B. et al. J. Org. Chem. 2005, 70, 8550.
2. Denmark, S. E. et al. Organic Reactions, Vol. 75, Denmark, S. E. ed., John Wiley and Sons, 233, 2011.

Additional Properties: 268
Dipole moment: 1.69 debye
?c of treated glass surface: 25 mN/m
Specific wetting surface area: 412 m2/g
?Hform: -463.5 kcal/mole
?Hvap: 6.8 kcal/mole
Specific heat: 0.25 cal/g/°
Relative hydrolysis rate versus SIV9220.0, vinyltrimethoxysilane; 0.05
Vapor pressure, 20°: 5 mm