VINYLMETHYLDICHLOROSILANE - LOW COLOR GRADE

Product Code: SIV9084.1
CAS No: 124-70-9
Pack Size
Quantity
Price
 
18 kg
Contact Us For Pricing
180 kg
Contact Us For Pricing

Product data and descriptions listed are typical values, not intended to be used as specification.

  • HMIS

    3-4-1-X

Safety

  • Packaging Under

    Nitrogen
  • Alkenylsilane Cross-Coupling Agent

    The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.

    2-Propenyltrimethylsilane; 2-Trimethylsilylprop-1-ene

  • Viscosity: 0.70 cSt
  • ΔHvap: 33.9 kJ/mol
  • Critical temperature: 272 °C
  • Coefficient of thermal expansion: 1.4 x 10-3
  • Reacts to vinylate aryl halides under NaOH-moderated conditions
  • Used as a tether in synthesis of C-glycosides
  • Standard grade available, SIV9084.0
  • Extensive review of silicon based cross-coupling agents: Denmark, S. E. et al. "Organic Reactions, Volume 75" Denmark, S. E. ed., John Wiley and Sons, 233, 2011
  • Silicon Chemistry, Articles

    Silicon-Based Formation of Carbon-Carbon Bonds – Larson

    Hatanaka and Hiyama first reported the palladium-catalyzed, fluoride-promoted reaction of aryl, alkenyl, allyl, and ethynyltrimethylsilanes with aryl, vinil and allyl halides to form the respective cross-coupled products