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Product Code: SIV9084.1

Cas No: 124-70-9

R&D quantities:

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Alkenylsilane Cross-Coupling Agent

The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.

2-Propenyltrimethylsilane; 2-Trimethylsilylprop-1-ene
  • Viscosity: 0.70 cSt
  • ΔHvap: 33.9 kJ/mol
  • Critical temperature: 272 °C
  • Coefficient of thermal expansion: 1.4 x 10-3
  • Reacts to vinylate aryl halides under NaOH-moderated conditions
  • Used as a tether in synthesis of C-glycosides
  • Standard grade available, SIV9084.0
  • Extensive review of silicon based cross-coupling agents: Denmark, S. E. et al. "Organic Reactions, Volume 75" Denmark, S. E. ed., John Wiley and Sons, 233, 2011
  • EINECS Number: 204-710-3

    Specific Gravity: 1.087

    HMIS Key: 3-4-1-X

    Hydrolytic Sensitivity: 8: reacts rapidly with moisture, water, protic solvents

    Refractive Index: 1.4270