3901-77-7

All structures are computer generated. Please rely on the product data below for placing your order. If you see any errors in structures, please email customer service so that they can be addressed.

1,3,5-TRIVINYL-1,3,5-TRIMETHYLCYCLOTRISILOXANE

Product Code: SIT8737.0

Cas No: 3901-77-7

R&D quantities:

25 g
$171.00
5 g
$43.00
2 kg
$3,846.00

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Alkenylsilane Cross-Coupling Agent

The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.

1,3,5-Trivinyl-1,3,5-trimethylcyclotrisiloxane; D’3; Trimethyltrivinylcyclotrisiloxane; Trivinyltrimethylcyclotrisiloxane; 2,4,6-Trimethyl-2,4,6-trivinylcyclotrisiloxane
  • Reagent formation of styrenes and dienes.
  • Undergoes “living” anion ring-opening polymerization
  • Reagent for vinylations via cross-coupling protocols
  • Extensive review of silicon based cross-coupling agents: Denmark, S. E. et al. "Organic Reactions, Volume 75" Denmark, S. E. ed., John Wiley and Sons, 233, 2011
  • Boiling Point: 80° / 20

    EINECS Number: 223-458-5

    Molecular Weight: 258.50

    Specific Gravity: 0.9669

    HMIS Key: 2-1-0-X

    Hydrolytic Sensitivity: 1: no significant reaction with aqueous systems

    Formula: C9H18O3Si3

    Refractive Index: 1.4215

    TSCA: TSCA

    Application: Reagent for vinylations via cross-coupling protocols.1,2

    Reference: 1. Denmark, S. E.; Wang, Z. J. Organomet. Chem. 2001, 624, 372.
    2. Denmark, S. E.; Butler, C. R. J. Am. Chem. Soc. 2008, 130, 3690.

    Additional Properties: Undergoes "living" anion ring-opening polymerization