To search by structure, left click in the box below to display the chemdraw toolbar. Then, draw the chemical structure of interest in the box using the toolbar. When your structure is complete, click “Search by Name” or “Search by SMILES” to generate the product name or SMILES respectively. This feature will search within the Gelest product database for matching chemical names or SMILES. Note: In cases where Gelest uses alternate chemical names, it may be necessary to search for the product of interest by its CAS#.
All structures are computer generated. Please rely on the product data below for placing your order. If you see any errors in structures, please email customer service so that they can be addressed.
N-(TRIMETHYLSILYL)IMIDAZOLE
Boiling Point: 99° / 14
EINECS Number: 242-040-3
Molecular Weight: 140.26
Specific Gravity: 0.956
Flashpoint: 40°C (104°F)
HMIS Key: 2-3-1-X
Hydrolytic Sensitivity: 7: reacts slowly with moisture/water
Formula: C6H12N2Si
Refractive Index: 1.4756
TSCA: TSCA
Application: Review of synthetic utility.1
Shown to open an epoxide in a syn fashion.2
Reference: 1. Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, Fuchs, P. L. Ed., John Wiley and Sons, Ltd., 2011, p. 640-645.
2. Adam, W. et al. J. Am. Chem. Soc. 1991, 113, 8005.
Fieser: F&F: Vol. 2, p 412; Vol. 3, p 148; Vol. 7, p 399; Vol. 11, p 575.
Additional Properties: Dipole moment: 4.64 debyepKb: 15.07Trimethylsilylation reagent specific to hydroxyl groups
Metal-Organics
Silanes