COMMERCIAL
18156-74-6

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N-(TRIMETHYLSILYL)IMIDAZOLE

Product Code: SIT8590.0

Cas No: 18156-74-6

R&D quantities:

100 g
$116.00
25 g
$37.00
2 kg
$718.00

Interested in a Commercial Order?

Boiling Point: 99° / 14

EINECS Number: 242-040-3

Molecular Weight: 140.26

Specific Gravity: 0.956

Flashpoint: 40°C (104°F)

HMIS Key: 2-3-1-X

Hydrolytic Sensitivity: 7: reacts slowly with moisture/water

Formula: C6H12N2Si

Refractive Index: 1.4756

TSCA: TSCA

Application: Review of synthetic utility.1
Shown to open an epoxide in a syn fashion.2

Reference: 1. Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, Fuchs, P. L. Ed., John Wiley and Sons, Ltd., 2011, p. 640-645.
2. Adam, W. et al. J. Am. Chem. Soc. 1991, 113, 8005.

Fieser: F&F: Vol. 2, p 412; Vol. 3, p 148; Vol. 7, p 399; Vol. 11, p 575.

Additional Properties: Dipole moment: 4.64 debye
pKb: 15.07
Trimethylsilylation reagent specific to hydroxyl groups