To search by structure, left click in the box below to display the chemdraw toolbar. Then, draw the chemical structure of interest in the box using the toolbar. When your structure is complete, click “Search by Name” or “Search by SMILES” to generate the product name or SMILES respectively. This feature will search within the Gelest product database for matching chemical names or SMILES. Note: In cases where Gelest uses alternate chemical names, it may be necessary to search for the product of interest by its CAS#.
All structures are computer generated. Please rely on the product data below for placing your order. If you see any errors in structures, please email customer service so that they can be addressed.
TRIMETHYLIODOSILANE
Boiling Point: 106-7°
EINECS Number: 240-171-0
Molecular Weight: 200.10
Alternative Name: TRIMETHYLSILYL IODIDE
Specific Gravity: 1.470
Flashpoint: -2°C (28°F)
HMIS Key: 3-4-1-X
Hydrolytic Sensitivity: 8: reacts rapidly with moisture, water, protic solvents
Formula: C3H9ISi
Refractive Index: 1.4742
TSCA: TSCA
Application: Key reviews.1,2
Reagent for cleavage of ethers, esters, lactones.3
Used to dechlorinate aryl chlorides.4
Allylates aldehydes in the presence of allyl chloride and tin tetraiodide (SNT7946).5
Reference: 1. Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, Fuchs, P. L. Ed., John Wiley and Sons, Ltd., 2011, p. 325-336.
2. Olah, G. et al. In Advances in Silicon Chemistry; Larson, G., Ed.; JAI Press: Greenwich, Co, 1991; Vol. 1, p.1.
3. DePew, K. M. et al. J. Org. Chem. 1999, 121, 11953.
4. Sako, M. et al. J. Org. Chem. 2001, 66, 3610.
5. Masuyama, Y. et al. Tetrahedron Lett. 2005, 46, 2861.
Fieser:
Additional Properties: Dipole moment: 2.46 debye?Hform: -52.2 kcal/moleStabilized with copper granulesVapor pressure, 25°: 40 mm
Silanes
Silanes
Bulk Metal-Organics and Silanes: Pharmaceutical & Organic Synthesis
Silicon-Based Blocking Agents
Enabling Synthetic Organic Transformations
Iodotrimethylsilane – Olah et al.