COMMERCIAL
16029-98-4

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TRIMETHYLIODOSILANE

Product Code: SIT8564.0

Cas No: 16029-98-4

R&D quantities:

100gm
$242.00
2.5kg
$1,387.50
25gm
$75.00

Boiling Point: 106-7°

EINECS Number: 240-171-0

Molecular Weight: 200.10

Alternative Name: TRIMETHYLSILYL IODIDE

Specific Gravity: 1.470

Flashpoint: -2°C (28°F)

HMIS Key: 3-4-1-X

Hydrolytic Sensitivity: 8: reacts rapidly with moisture, water, protic solvents

Formula: C3H9ISi

Refractive Index: 1.4742

TSCA: TSCA

Application: Key reviews.1,2
Reagent for cleavage of ethers, esters, lactones.3
Used to dechlorinate aryl chlorides.4
Allylates aldehydes in the presence of allyl chloride and tin tetraiodide (SNT7946).5

Reference: 1. Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, Fuchs, P. L. Ed., John Wiley and Sons, Ltd., 2011, p. 325-336.
2. Olah, G. et al. In Advances in Silicon Chemistry; Larson, G., Ed.; JAI Press: Greenwich, Co, 1991; Vol. 1, p.1.
3. DePew, K. M. et al. J. Org. Chem. 1999, 121, 11953.
4. Sako, M. et al. J. Org. Chem. 2001, 66, 3610.
5. Masuyama, Y. et al. Tetrahedron Lett. 2005, 46, 2861.

Fieser:

Additional Properties: Dipole moment: 2.46 debye
?Hform: -52.2 kcal/mole
Stabilized with copper granules
Vapor pressure, 25°: 40 mm