To search by structure, left click in the box below to display the chemdraw toolbar. Then, draw the chemical structure of interest in the box using the toolbar. When your structure is complete, click “Search by Name” or “Search by SMILES” to generate the product name or SMILES respectively. This feature will search within the Gelest product database for matching chemical names or SMILES. Note: In cases where Gelest uses alternate chemical names, it may be necessary to search for the product of interest by its CAS#.
- Einecs Number 233-042-5
- HMIS 3-4-2-X
- Molecular Formula HCl3Si
- Molecular Weight (g/mol) 135.45
- Purity (%) 99%
- TSCA Yes
- Delta H Vaporization (kJ/mol) 6.7 kcal/mole
- Autoignition Temp (˚C) 215
- Boiling Point (˚C/mmHg) 31.9
- Density (g/mL) 1.3417
- Flash Point (˚C) -13
- Melting Point (˚C) -128°
- Refractive Index @ 20˚C 1.4020
- Specific Wetting (m2/g) 240
- Viscosity at 25 ˚C (cSt) 0.23
Generates chlorosilylene chemistry.1
Carries out thionation and selenation of amides and lactams with elemental sulfur or selenium, respectively.2
F&F: Vol. 3, p 298; Vol. 4, p 525; Vol. 5, p 688; Vol. 7, p 606; Vol. 11, p 553; Vol. 13, p 322; Vol. 14, p 82; Vol. 18, p 373.
1. Jung, I. N. et al. Organometallics 2003, 22, 2551.
2. Shibahara, F. et al. Org. Lett. 2009, 11, 3064.
Tri-substituted Silane Reducing Agent
Organosilanes are hydrocarbon-like and possess the ability to serve as both ionic and free-radical reducing agents. These reagents and their reaction by-products are safer and more easily handled and disposed than many other reducing agents. The metallic nature of silicon and its low electronegativity relative to hydrogen lead to polarization of the Si-H bond yielding a hydridic hydrogen and a milder reducing agent compared to aluminum-, boron-, and other metal-based hydrides. A summary of some key silane reductions are presented in Table 1 of the Silicon-Based Reducing Agents brochure.
Trichlorosilane; Silicochloroform hydrotrichlorosilane; Silicon chloride hydride; Trichloromonosilane
SURFACE TRANSPORT ONLY, UPS FORBIDDEN
AIR TRANSPORT FORBIDDEN