15933-59-2

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1,1,3,3-TETRAMETHYLDISILAZANE

Product Code: SIT7542.0

Cas No: 15933-59-2

R&D quantities:

100gm
$143.00
25gm
$44.00

Boiling Point: 99-100°

EINECS Number: 240-072-2

Molecular Weight: 133.34

Specific Gravity: 0.766

Flashpoint: 11°C (52°F)

HMIS Key: 3-4-1-X

Hydrolytic Sensitivity: 7: reacts slowly with moisture/water

Formula: C4H15NSi2

Refractive Index: 1.4044

TSCA: TSCA

Application: Review of synthetic utility.1
Converts unsaturated alcohols to diols.2
Converts homopropargylic alcohols to ?-hydroxy ketones in a three-step process.3
Employed in the silylation/hydrosilylation of allylic alcohols leading to useful cyclic alkoxysilane intermediates.4

Reference: 1. Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, Fuchs, P. L. Ed., John Wiley and Sons, Ltd., 2011, p. 488-490.
2. Tamao, K. et al. J. Am. Chem. Soc. 1988, 110, 3712.
3. Marshall, J. A.; Yanik, M.W. Org. Lett. 2000, 2, 2173.
4. Tamao, K. et al. J. Am. Chem. Soc. 1986, 108, 6090.

Fieser:

Additional Properties: 208
Forms dimethylsilyl ethers with greater volatility than trimethylsilyl ethers