POTASSIUM TRIMETHYLSILANOLATE, 2M in tetrahydrofuran (26-29 wt %)

Product Code: SIP6901.2
CAS No: 10519-96-7
SDS Sheets: EU | US
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10519-96-7
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Pack Size
Quantity
Price
 
25 g
$285.00
2 kg
$2,286.00

Prices listed are EXW price (Morrisville, PA US) in USD. Prices vary depending on currency and Incoterms.

Product data and descriptions listed are typical values, not intended to be used as specification.

  • Einecs Number

    234-062-7
  • HMIS

    3-4-1-X
  • Molecular Formula

    C3H9KOSi
  • Molecular Weight (g/mol)

    128.29
  • TSCA

    Yes
  • Boiling Point (˚C/mmHg)

    NA
  • Density (g/mL)

    0.91
  • Flash Point (˚C)

    -14 °C

Additional Properties

  • Hydrolytic Sensitivity

    7: reacts slowly with moisture/water

    • Application

    Reviewed.1
    Used in the vinylation of aromatic bromides.2
    Employed in a silicon-based cross-coupling step in a synthesis of papulacandin D.3
    Converts methyl esters to potassium salts of carboxylic acids.4
    Promoter for the silicon-based cross-coupling of vinylsiloxanes with aryl iodides.2,5

    Reference

    1. Bennett, C. E. in e-EROS Encyclopedia of Reagents for Organic Synthesis, 2007.
    2. Denmark, S. E.; Butler, C. R. Org. Synth. 2009, 86, 274.
    3. Denmark, S. E.; Regens, C. S.; Kobayashi, T. J. Am. Chem. Soc. 2007, 129, 2774.
    4. Minta, E. et al. Tetrahedron Lett. 2005, 46, 1795.
    5. Denmark, S. E.; Butler, C. R. J. Am. Chem. Soc. 2008, 130, 3690.

    Safety

  • Packaging Under

    Nitrogen