POTASSIUM TRIMETHYLSILANOLATE, 2M in tetrahydrofuran (26-29 wt %)

Product Code: SIP6901.2
CAS No: 10519-96-7
SDS Sheets: EU | US
Pack Size
Quantity
Price
 
25 g
$108.00
2 kg
$1,524.00
16 kg
$7,488.00

Product data and descriptions listed are typical values, not intended to be used as specification.

  • Einecs Number

    234-062-7
  • HMIS

    3-4-1-X
  • Molecular Formula

    C3H9KOSi
  • Molecular Weight (g/mol)

    128.29
  • TSCA

    Yes
  • Boiling Point (˚C/mmHg)

    NA
  • Density (g/mL)

    0.91
  • Flash Point (˚C)

    -14 °C

Additional Properties

  • Hydrolytic Sensitivity

    7: reacts slowly with moisture/water
  • Application

    Reviewed.1
    Used in the vinylation of aromatic bromides.2
    Employed in a silicon-based cross-coupling step in a synthesis of papulacandin D.3
    Converts methyl esters to potassium salts of carboxylic acids.4
    Promoter for the silicon-based cross-coupling of vinylsiloxanes with aryl iodides.2,5

    Reference

    1. Bennett, C. E. in e-EROS Encyclopedia of Reagents for Organic Synthesis, 2007.
    2. Denmark, S. E.; Butler, C. R. Org. Synth. 2009, 86, 274.
    3. Denmark, S. E.; Regens, C. S.; Kobayashi, T. J. Am. Chem. Soc. 2007, 129, 2774.
    4. Minta, E. et al. Tetrahedron Lett. 2005, 46, 1795.
    5. Denmark, S. E.; Butler, C. R. J. Am. Chem. Soc. 2008, 130, 3690.

    Safety

  • Packaging Under

    Nitrogen