768-32-1

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PHENYLTRIMETHYLSILANE

Product Code: SIP6823.0

Cas No: 768-32-1

R&D quantities:

25 g
$81.00
Arylsilane Cross-Coupling Agent

The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.

Phenyltrimethylsilane; Trimethylsilylbenzene
  • Viscosity: 1.1 cSt
  • Dipole moment: 0.44 debye
  • Alternative to phenyltriethoxysilane or phenyltrimethoxysilane for the cross-coupling of a phenyl group
  • Used to silylate and determine acid number of hydroxyl groups in aluminosilicate
  • Extensive review of silicon based cross-coupling agents: Denmark, S. E. et al. "Organic Reactions, Volume 75" Denmark, S. E. ed., John Wiley and Sons, 233, 2011
  • Boiling Point: 169-70°

    EINECS Number: 212-192-5

    Molecular Weight: 150.30

    Specific Gravity: 0.872

    Flashpoint: 40°C (104°F)

    HMIS Key: 2-2-0-X

    Hydrolytic Sensitivity: 1: no significant reaction with aqueous systems

    Formula: C9H14Si

    Refractive Index: 1.4908

    TSCA: TSCA

    Application: Used to silylate and determine acid number of hydroxyl groups in aluminosilicate.1

    Reference: 1. Song, W. et al. J. Am. Chem. Soc. 2003, 125, 13964.

    Additional Properties: Dipole moment: 0.44 debye