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- Einecs Number 212-192-5
- HMIS 2-2-0-X
- Molecular Formula C9H14Si
- Molecular Weight (g/mol) 150.30
- TSCA Yes
- Boiling Point (˚C/mmHg) 169-170
- Density (g/mL) 0.872
- Flash Point (˚C) 40
- Refractive Index @ 20˚C 1.4908
- Viscosity at 25 ˚C (cSt) 1.1
Used to silylate and determine acid number of hydroxyl groups in aluminosilicate.1
1. Song, W. et al. J. Am. Chem. Soc. 2003, 125, 13964.
Arylsilane Cross-Coupling Agent
The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.
Silicon Chemistry, Articles
Hatanaka and Hiyama first reported the palladium-catalyzed, fluoride-promoted reaction of aryl, alkenyl, allyl, and ethynyltrimethylsilanes with aryl, vinil and allyl halides to form the respective cross-coupled products