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25 g
$81.00
2 kg
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Product data and descriptions listed are typical values, not intended to be used as specification.

  • Einecs Number

    212-192-5
  • HMIS

    2-2-0-X
  • Molecular Formula

    C9H14Si
  • Molecular Weight (g/mol)

    150.30
  • TSCA

    Yes
  • Boiling Point (˚C/mmHg)

    169-170
  • Density (g/mL)

    0.872
  • Flash Point (˚C)

    40
  • Refractive Index @ 20˚C

    1.4908
  • Viscosity at 25 ˚C (cSt)

    1.1

Additional Properties

  • Hydrolytic Sensitivity

    1: no significant reaction with aqueous systems
  • Application

    Used to silylate and determine acid number of hydroxyl groups in aluminosilicate.1

    Reference

    1. Song, W. et al. J. Am. Chem. Soc. 2003, 125, 13964.

    Safety

  • Packaging Under

    Nitrogen
  • Arylsilane Cross-Coupling Agent

    The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.

    Phenyltrimethylsilane; Trimethylsilylbenzene

  • Viscosity: 1.1 cSt
  • Dipole moment: 0.44 debye
  • Alternative to phenyltriethoxysilane or phenyltrimethoxysilane for the cross-coupling of a phenyl group
  • Used to silylate and determine acid number of hydroxyl groups in aluminosilicate
  • Extensive review of silicon based cross-coupling agents: Denmark, S. E. et al. "Organic Reactions, Volume 75" Denmark, S. E. ed., John Wiley and Sons, 233, 2011
  • Silicon Chemistry, Articles

    Silicon-Based Formation of Carbon-Carbon Bonds – Larson

    Hatanaka and Hiyama first reported the palladium-catalyzed, fluoride-promoted reaction of aryl, alkenyl, allyl, and ethynyltrimethylsilanes with aryl, vinil and allyl halides to form the respective cross-coupled products