LITHIUM HEXAMETHYLDISILAZIDE, 0.85M in hexane (19-21 wt %)

Product Code: SIL6467.2
CAS No: 4039-32-1
SDS Sheets: EU | US
COMMERCIAL
4039-32-1
Pack Size
Quantity
Price
 
100 g
$200.00
2.5 kg
$515.00
12.5 kg
$1,512.00
135 kg
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Prices listed are EXW price (Morrisville, PA US) in USD. Prices vary depending on currency and Incoterms.

Product data and descriptions listed are typical values, not intended to be used as specification.

  • HMIS

    3-4-1-X
  • Molecular Formula

    C6H18LiNSi2
  • Molecular Weight (g/mol)

    167.33
  • TSCA

    Yes
  • Boiling Point (˚C/mmHg)

    NA
  • Density (g/mL)

    0.716
  • Flash Point (˚C)

    -23 °C

Additional Properties

  • Hydrolytic Sensitivity

    7: reacts slowly with moisture/water
  • Application

    Review of synthetic utility.1
    Used in the use of chloroform in the trichloromethylation of a ketone in a scaled-up synthesis of ?-secretase inhibitor, spiropiperidine.2

    Reference

    1. Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, Fuchs, P. L. Ed., John Wiley and Sons, Ltd., 2011, p. 356-367.
    2. Henegar, K. E. et al. Org. Process. Res. Dev. 2013, 17, 985.

    Safety

  • Packaging Under

    Nitrogen