IODOMETHYLTRIMETHYLSILANE

Product Code: SII6450.0
CAS No: 4206-67-1
SDS Sheets: EU | US
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10 g
$63.00
50 g
$248.00
2 kg
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20 kg
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Product data and descriptions listed are typical values, not intended to be used as specification.

  • Einecs Number

    224-123-6
  • HMIS

    2-3-0-X
  • Molecular Formula

    C4H11ISi
  • Molecular Weight (g/mol)

    214.12
  • TSCA

    Yes (L)
    Low Volume Exemption
  • Boiling Point (˚C/mmHg)

    140-2°
  • Density (g/mL)

    1.441
  • Flash Point (˚C)

    31°C (88°F)
  • Refractive Index @ 20˚C

    1.4910

Additional Properties

  • Hydrolytic Sensitivity

    3: reacts with aqueous base
  • Application

    Review of synthetic utility.1
    Employed in silyl-methylation of alkynes.2
    Converts aldehydes, ketones, ?,?-enones to silyl enol ethers.3
    Intermediate for allylic silane synthon, 2-(trimethylsilyl)ethyltriphenylphosphonium iodide.4
    Useful for the introduction of the trimethylsilylmethyl group.5

    Reference

    1. Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, Fuchs, P. L. Ed., John Wiley and Sons, Ltd., 2011, p. 323-336.
    2. Schmid, R. et al. J. Am. Chem. Soc. 1980, 102, 5122.
    3. Cazeau, P. et al. Tetrahedron 1987, 43, 2075, 2089.
    4. Fleming, I. et al. Synthesis 1979, 446.
    5. Vedejs, E. J. Org. Chem. 1985, 50, 2170.

    Safety

  • Packaging Under

    Nitrogen