74612-30-9

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(HEPTADECAFLUORO-1,1,2,2-TETRAHYDRODECYL)DIMETHYLCHLOROSILANE

Product Code: SIH5840.4

Cas No: 74612-30-9

R&D quantities:

25 g
$242.00
5 g
$61.00
Specialty Silicon-Based Blocking Agent

Used as a protecting group for reactive hydrogens in alcohols, amines, thiols, and carboxylic acids. Organosilanes are hydrogen-like, can be introduced in high yield, and can be removed under selective conditions. They are stable over a wide range of reaction conditions and can be removed in the presence of other functional groups, including other protecting groups. The tolerance of silylated alcohols to chemical transformations summary is presented in Table 1 of the Silicon-Based Blocking Agents brochure.

(Heptadecafluoro-1,1,2-2-tetrahydradecyl)dimethylchlorosilane; Perfluorodecyl-1H,1H,2H,2H-dimethylchlorosilane; (1H,1H,2H,2H-Perfluorodecyl)dimethylchlorosilane
  • Packaged over copper powder
  • Potential blocking agent for fluorous phase synthesis
  • Summary of selective deprotection conditions is provided in Table 7 through Table 20 of the Silicon-Based Blocking Agents brochure
  • Treated onto silica to prepare a fluorinated surface for the embedding of a catalyst for Bonded Fluorous Phase Catalysis (BFPC) used in dehydrogenative silylation of alcohols
  • Forms self-assembled monolayer resists that align nanowire arrays
  • Boiling Point: 197-8°

    Molecular Weight: 540.72

    Alternative Name: PERFLUORODECYL-1H,1H,2H,2H-DIMETHYLCHLOROSILANE

    Specific Gravity: 1.51

    HMIS Key: 3-2-1-X

    Hydrolytic Sensitivity: 8: reacts rapidly with moisture, water, protic solvents

    Formula: C12H10ClF17Si

    Refractive Index: 1.3410

    Application: Treated onto silica to prepare a fluorinated surface for the embedding of a catalyst for Bonded Fluorous Phase Catalysis (BFPC) used in dehydrogenative silylation of alcohols.1
    Forms self-assembled monolayer resists that align nanowire arrays.2

    Reference: 1. Biffis, A.; Zecca, M.; Basato, M. Green Chemistry, 2003, 5, 170 and Biffis, A.; Braga, M.; Basato, M. Adv. Synth. Catal. 2004, 346, 451.
    2. Takahashi, T. et al. J. Am. Chem. Soc. 2009, 131, 2102.

    Additional Properties: Packaged over copper powder