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ETHYLTRICHLOROSILANE
Boiling Point: 100-1°
EINECS Number: 204-072-6
Melting Point: -106°
Molecular Weight: 163.51
Specific Gravity: 1.237
Flashpoint: 27°C (81°F)
HMIS Key: 3-3-1-X
Hydrolytic Sensitivity: 8: reacts rapidly with moisture, water, protic solvents
Formula: C2H5Cl3Si
Refractive Index: 1.4260
TSCA: TSCA
Application: Employed in the cobalt-catalyzed Diels-Alder approach to 1,3-disubstituted and 1,2,3-trisubstituted benzenes.1
Reference: 1. Hilt, G.; Danz, M. Synthesis 2008, 2257.
Fieser: F&F: Vol. 16, p 98.
Additional Properties: Dipole moment: 2.1 debye?Hcomb: -644 kcal/moleCritical temperature: 287°?Hform: -20 kcal/mole?Hvap: 9.0 kcal/mole?Hfus: 7.0 kJ/moleCoefficient of thermal expansion: 1.5 x 10-3Vapor pressure, 20°: 26 mmVapor pressure, 30.4°: 66 mm
Silanes
Silanes
Hydrophobicity, Hydrophilicity and Silanes – Arkles