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- Einecs Number 234-060-6
- HMIS 2-4-0-X
- Molecular Formula C6H12Si
- Molecular Weight (g/mol) 112.25
- TSCA No
- Boiling Point (˚C/mmHg) 82
- Density (g/mL) 0.7337
- Flash Point (˚C) 8 °C
- Refractive Index @ 20˚C 1.4176
Forms copolymers with maleic anhydride.1
Forms polyamine macrocycles on reaction with Li dialkylamides, e.g. LiEtNCH2CH2NEtLi.2
Forms "smart" silamine polymers on reaction with 3,6-diazaoctane.3
Potential vinyl nucleophile in cross-coupling reactions.4
1. Butler, G. et al. J. Polym. Sci. 1970, A1-8, 523.
2. Nagasaki, Y. et al. Chem. Lett. 1993, 1825.
3. Nagasaki, Y. et al. Chemtech 1997, 27(3), 23.
4. Larson, G. L. “Silicon-Based Cross-Coupling Reagents” Gelest, Inc. 2011.
Alkenylsilane Cross-Coupling Agent
The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.
Silicon Chemistry, Articles
Hatanaka and Hiyama first reported the palladium-catalyzed, fluoride-promoted reaction of aryl, alkenyl, allyl, and ethynyltrimethylsilanes with aryl, vinil and allyl halides to form the respective cross-coupled products