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5 g
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25 g
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1.5 kg
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12 kg
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Product data and descriptions listed are typical values, not intended to be used as specification.

  • Einecs Number

    234-060-6
  • HMIS

    2-4-0-X
  • Molecular Formula

    C6H12Si
  • Molecular Weight (g/mol)

    112.25
  • Boiling Point (˚C/mmHg)

    82°
  • Density (g/mL)

    0.7337
  • Flash Point (˚C)

    8°C (46°F)
  • Refractive Index @ 20˚C

    1.4176

Additional Properties

  • Hydrolytic Sensitivity

    1: no significant reaction with aqueous systems
  • Application

    Forms copolymers with maleic anhydride.1
    Forms polyamine macrocycles on reaction with Li dialkylamides, e.g. LiEtNCH2CH2NEtLi.2
    Forms "smart" silamine polymers on reaction with 3,6-diazaoctane.3
    Potential vinyl nucleophile in cross-coupling reactions.4

    Reference

    1. Butler, G. et al. J. Polym. Sci. 1970, A1-8, 523.
    2. Nagasaki, Y. et al. Chem. Lett. 1993, 1825.
    3. Nagasaki, Y. et al. Chemtech 1997, 27(3), 23.
    4. Larson, G. L. “Silicon-Based Cross-Coupling Reagents” Gelest, Inc. 2011.

    Safety

  • Packaging Under

    Nitrogen
  • Alkenylsilane Cross-Coupling Agent

    The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.

    Divinyldimethylsilane; Diethenyldimethylsilane

  • Potential vinyl donor in cross-coupling reactions
  • Forms copolymers with maleic anhydride
  • Forms polyamine macrocycles on reaction with Li dialkylamides, e.g. LiEtNCH2CH2NEtLi
  • Forms “smart” silamine polymers on reaction with 3,6-diazaoctane
  • Potential vinyl nucleophile in cross-coupling reactions
  • Extensive review of silicon based cross-coupling agents: Denmark, S. E. et al. "Organic Reactions, Volume 75" Denmark, S. E. ed., John Wiley and Sons, 233, 2011
  • Silicon Chemistry, Articles

    Silicon-Based Formation of Carbon-Carbon Bonds – Larson

    Hatanaka and Hiyama first reported the palladium-catalyzed, fluoride-promoted reaction of aryl, alkenyl, allyl, and ethynyltrimethylsilanes with aryl, vinil and allyl halides to form the respective cross-coupled products