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Product Code: SID4552.0

Cas No: 144-79-6

R&D quantities:

2.5 kg
100 g
25 g
1 kg

Boiling Point: 295°

EINECS Number: 205-639-0

Melting Point: -22°

Molecular Weight: 232.78

Specific Gravity: 1.128

Flashpoint: 141°C (286°F)

HMIS Key: 3-1-1-X

Hydrolytic Sensitivity: 8: reacts rapidly with moisture, water, protic solvents

Formula: C13H13ClSi

Refractive Index: 1.5742


Application: Review of synthetic utility.1
?-Silylates esters, lactones; precursors to silyl enolates.2
C-Silylates carbamates as shown in the enantioselective example w/ a neryl carbamate.3

Reference: 1. Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, Fuchs, P. L. Ed., John Wiley and Sons, Ltd., 2011, p. 381-388.
2. Larson, G. L.; Fuentes,L. M. J. Am. Chem. Soc. 1981, 103, 2418.
3. Duvold, T. et al. Biorg. Med. Chem. Lett. 2002, 12, 3569 and references therein.

Fieser: F&F: Vol. 10, p 91; Vol. 12, p 321; Vol. 13, p 74.

Additional Properties: Surface tension: 40.0 mN/m
?Hvap: 149 kcal/mole
Thermal conductivity: 0.112 W/m°C
Vapor pressure, 125°: 3 mm