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Boiling Point: 295°
EINECS Number: 205-639-0
Melting Point: -22°
Molecular Weight: 232.78
Specific Gravity: 1.128
Flashpoint: 141°C (286°F)
HMIS Key: 3-1-1-X
Hydrolytic Sensitivity: 8: reacts rapidly with moisture, water, protic solvents
Refractive Index: 1.5742
Application: Review of synthetic utility.1
?-Silylates esters, lactones; precursors to silyl enolates.2
C-Silylates carbamates as shown in the enantioselective example w/ a neryl carbamate.3
Reference: 1. Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, Fuchs, P. L. Ed., John Wiley and Sons, Ltd., 2011, p. 381-388.
2. Larson, G. L.; Fuentes,L. M. J. Am. Chem. Soc. 1981, 103, 2418.
3. Duvold, T. et al. Biorg. Med. Chem. Lett. 2002, 12, 3569 and references therein.
Fieser: F&F: Vol. 10, p 91; Vol. 12, p 321; Vol. 13, p 74.
Additional Properties: Surface tension: 40.0 mN/m?Hvap: 149 kcal/moleThermal conductivity: 0.112 W/m°CVapor pressure, 125°: 3 mm