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Product Code: SID3398.0

Cas No: 996-50-9

R&D quantities:

100 g
25 g
2 kg

Boiling Point: 126-7°

EINECS Number: 213-637-6

Melting Point: -10°

Molecular Weight: 145.32

Alternative Name: TMSDEA

Specific Gravity: 0.7627

Flashpoint: 10°C (50°F)

HMIS Key: 3-4-1-X

Hydrolytic Sensitivity: 7: reacts slowly with moisture/water

Formula: C7H19NSi

Refractive Index: 1.4109


Application: Review of synthetic utility.1
Reacts with benzynes and aldehydes to form o-aminobenzyl alcohols.2
Provides a convenient synthesis of enoltrimethylsilyl ethers.3

Reference: 1. Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, Fuchs, P. L. Ed., John Wiley and Sons, Ltd., 2011, p. 598-599.
2. Yoshida, H. et al. Org. Lett. 2007, 9, 3367.
3. Yamamoto, Y.; Matui, C. Organometallics 1997, 16, 2204.

Fieser: F&F: Vol. 3, p 317; Vol. 4, p 544; Vol. 6, p 634; Vol. 18, p 382.

Additional Properties: ?Hform: -87.7 kcal/mole
Silylation reagent