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Boiling Point: 73-5° / .35
Molecular Weight: 440.46
Specific Gravity: 1.358
Flashpoint: 90°C (194°F)
HMIS Key: 3-2-1-X
Hydrolytic Sensitivity: 8: reacts rapidly with moisture, water, protic solvents
Refractive Index: 1.3975
Application: Review of synthetic utility.1
Reagent for protection of diols.2
Used to doubly block sialic acid for use in efficient silylation reactions.3
Can protect diols and be regioselectively mono-deprotected.4
Reference: 1. Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, Fuchs, P. L. Ed., John Wiley and Sons, Ltd., 2011, p. 209-222.
2. Corey, E. J.; Hopkins, P. B. Tetrahedron Lett. 1982, 23, 4871.
3. Hanshima, S. Eur. J. Org. Chem. 2009, 4215.
4. Yu, M.; Pagenkopf, B. L. J. Org. Chem. 2002, 67, 4553.