Additional Properties
- Einecs Number 218-939-1
- Synonyms 1,1-DIMETHYLSILETANE
- HMIS 2-4-0-X
- Molecular Formula C5H12Si
- Molecular Weight (g/mol) 100.24
- Purity (%) 97%
- TSCA Yes
- Boiling Point (˚C/mmHg) 82
- Density (g/mL) 0.775
- Flash Point (˚C) -5 °C
- Refractive Index @ 20˚C 1.4290
Application
Review of synthetic utility.1
Undergoes insertion reactions.2
Undergoes polymerization.3
Undergoes reductive silylation of aldehydes.4
Reacts w/ aldehydes to form 3-substituted 1-sila-2-oxacycohexanes.5
Reference
1. Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, Fuchs, P. L. Ed., John Wiley and Sons, Ltd., 2011, p. 261-262.
2. Matsumoto, K. et al. Tetrahedron Lett. 1990, 31, 6055.
3. Weyenberg, D. et al. J. Org. Chem. 1965, 30, 2618.
4. Hirano, H. et al. Org. Lett. 2006, 8, 483.
5. Takeyama, Y. et al. Tetrahedron Lett. 1990, 31, 6059.
Safety