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p-(t-BUTYLDIMETHYLSILOXY)STYRENE
Alkenylsilane Cross-Coupling Agent
The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.
p-(t-Butyldimethylsiloxy)styrene; p-Vinyl-t-Butyldimethylbenzene
Specific Gravity: 0.922
HMIS Key: 2-2-0-X
Hydrolytic Sensitivity: 7: reacts slowly with moisture/water
Formula: C14H22OSi
Refractive Index: 1.5091
Application: Undergoes radical1,2 and anionic polymerization.3,4,5
Reference: 1. Packirisamy, S. et al. J. Polym. Sci., Part A: Polym. Chem. 1989, 27, 2811.
2. Xu, Y. et al. Polymer 1991, 32, 3103.
3. Hirao, A. et al. Makromol. Chem., Rapid Commun. 1982, 3, 941.
4. Hirao, A. et al. Makromol. Chem. 1985, 186, 1157.
5. Ito, H. et al. Polym. Mater. Sci. Eng. Preprints 1993, 68, 12.