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Diamino Functional Trialkoxy Silane
Silane coupling agents have the ability to form a durable bond between organic and inorganic materials to generate desired heterogeneous environments or to incorporate the bulk properties of different phases into a uniform composite structure. The general formula has two classes of functionality. The hydrolyzable group forms stable condensation products with siliceous surfaces and other oxides such as those of aluminum, zirconium, tin, titanium, and nickel. The organofunctional group alters the wetting or adhesion characteristics of the substrate, utilizes the substrate to catalyze chemical transformations at the heterogeneous interface, orders the interfacial region, or modifies its partition characteristics, and significantly effects the covalent bond between organic and inorganic materials.
N-(2-Aminoethyl)-3-aminopropyltrimethoxysilane; N-[3-(Trimethoxysilyl)propyl]ethylenediamine; DAMO
EINECS Number: 217-164-6
Alternative Name: N-[3-(TRIMETHOXYSILYL)PROPYL]ETHYLENEDIAMINE; DAMO
Specific Gravity: 1.019
Flashpoint: 150°C (302°F)
HMIS Key: 3-1-1-X
Hydrolytic Sensitivity: 7: reacts slowly with moisture/water
Refractive Index: 1.450
Application: Used in the immobilization of copper (II) catalyst on silica.1
Used together w/ SID3396.0 to anchor PdCl2 catalyst to silica for acceleration of the Tsuji-Trost reaction.2
Reference: 1. Wu, Q.; Wang, L. Synthesis 2008, 2007.
2. Noda, H. et al. Angew. Chem., Int. Ed. Engl.2012, 51, 8017.
Additional Properties: 300Surface tension: 36.5 mN/mCoefficient of thermal expansion: 0.8 x 10-3Contains 2-6% N,N’-BIS[(TRIMETHOXYSILYL)PROPYL]ETHYLENEDIAMINECoupling agent for polyamides, polycarbonates (e.g. in CDs), polyesters and copper/brass adhesion