(S,S)-2-ALLYL-2-CHLORO-3,4-DIMETHYL-5-PHENYL-[1,3,2]-OXAZASILOLIDINE

Product Code: SIA0433.0
CAS No: 447440-43-9
SDS Sheets: EU | US
Pack Size
Quantity
Price
 
5 g
$238.00

Product data and descriptions listed are typical values, not intended to be used as specification.

  • Synonyms

    1-OXA-3-AZA-2-SILACYCLOPENTANE, 2-CHLORO-3,4-DIMETHYL-5-PHENYL-2-(2-PROPENYL), (4S,5S)
  • HMIS

    3-2-1-X
  • Molecular Formula

    C13H18ClNOSi
  • Molecular Weight (g/mol)

    267.82
  • Purity (%)

    97%
  • TSCA

    No
  • Boiling Point (˚C/mmHg)

    120° / 0.1
  • Density (g/mL)

    1.01
  • Refractive Index @ 20˚C

    1.5177

Additional Properties

  • Hydrolytic Sensitivity

    8: reacts rapidly with moisture, water, protic solvents
  • Application

    Used in the enantioselective allylation of aldehydes and imines.1,2

    Reference

    1. Kinnaird, J. W. A. et al. J. Am. Chem. Soc. 2002, 124, 7920.
    2. Berger, R. et al. J. Am. Chem. Soc. 2003, 125, 9596.

    Safety

  • Packaging Under

    Nitrogen