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DIETHYLZINC, 1M in heptane (16-17 wt %)
EINECS Number: 209-161-3
Specific Gravity: 0.740
Flashpoint: -4°C (25°F)
HMIS Key: 3-4-2-X
Hydrolytic Sensitivity: 8: reacts rapidly with moisture, water, protic solvents
Application: Review of carbozincation.1
Review of asymmetric addition of diorgaozinc reagents to aldehydes and prochiral ketones.2
Review of conjugate addition of organozinc reagents to a,b-unsaturated carbonyls.3
Reference: 1. Murakami, K.; Yorimitsu, H. Beilstein J. Org. Chem. 2013, 9, 278.
2. Binder, C. M.; Singaram, B. Org. Prep. Proc. Int. 2011, 43, 139.
3. Lopez, F.; Feringa, B. L. in Asymmetric Synthesis, Christmann, M.; Brase, S. Eds. Wiley and Sons.
Additional Properties: 16 - 17 wt%