To search by structure, left click in the box below to display the chemdraw toolbar. Then, draw the chemical structure of interest in the box using the toolbar. When your structure is complete, click “Search by Name” or “Search by SMILES” to generate the product name or SMILES respectively. This feature will search within the Gelest product database for matching chemical names or SMILES. Note: In cases where Gelest uses alternate chemical names, it may be necessary to search for the product of interest by its CAS#.
All structures are computer generated. Please rely on the product data below for placing your order. If you see any errors in structures, please email customer service so that they can be addressed.
DIPHENYLPHOSPHORYL AZIDE
Product data and descriptions listed are typical values, not intended to be used as specification.
EINECS Number: 247-644-0
Specific Gravity: 1.277
HMIS Key: 3-2-1-X
Hydrolytic Sensitivity: 7: reacts slowly with moisture/water
Formula: C12H10N3O3P
Refractive Index: 1.5520
Application: Reviewed along with other azides.1
Employed in preparation of macrocyclic lactams.2
Reagent for aziridation of olefins in presence of catalysts.3
Used as a reagent for a modified Curtius reaction.4
Reference: 1. Swamy, K. C. K. et al. Chem. Rev. 2009, 109, 2551.
2. Qian, L. et al. Tetrahedron Lett. 1990, 31, 6469.
3. Ikeda, L. I. et al. Synthesis 1980, 650.
4. Shiiori, T.; Ninomiya, K.; Yamada, S. J. Am. Chem. Soc. 1972, 94, 6203.
Fieser: F&F: Vol. 4, p 210; Vol. 5, p 280; Vol. 7, p 138; Vol. 8, p 211; Vol. 10, p 173, Vol. 16, p 160.
Metal-Organics
Metal-Organics
Bulk Metal-Organics and Silanes: Pharmaceutical & Organic Synthesis