DIPHENYLPHOSPHORYL AZIDE

Product Code: OMPH056
CAS No: 26386-88-9
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26386-88-9
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25 g
$110.00
2 kg
$1,332.00
20 kg
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Product data and descriptions listed are typical values, not intended to be used as specification.

  • Einecs Number

    247-644-0
  • HMIS

    3-2-1-X
  • Molecular Formula

    C12H10N3O3P
  • Molecular Weight (g/mol)

    275.20
  • Purity (%)

    97%
  • TSCA

    No
  • Boiling Point (˚C/mmHg)

    157° / 0.17
  • Density (g/mL)

    1.277
  • Refractive Index @ 20˚C

    1.5520

Additional Properties

  • Hydrolytic Sensitivity

    7: reacts slowly with moisture/water

    • Application

    Reviewed along with other azides.1
    Employed in preparation of macrocyclic lactams.2
    Reagent for aziridation of olefins in presence of catalysts.3
    Used as a reagent for a modified Curtius reaction.4

    Fieser

    F&F: Vol. 4, p 210; Vol. 5, p 280; Vol. 7, p 138; Vol. 8, p 211; Vol. 10, p 173, Vol. 16, p 160.

    Reference

    1. Swamy, K. C. K. et al. Chem. Rev. 2009, 109, 2551.
    2. Qian, L. et al. Tetrahedron Lett. 1990, 31, 6469.
    3. Ikeda, L. I. et al. Synthesis 1980, 650.
    4. Shiiori, T.; Ninomiya, K.; Yamada, S. J. Am. Chem. Soc. 1972, 94, 6203.

    Safety

  • Packaging Under

    Nitrogen