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- Einecs Number 247-644-0
- HMIS 3-2-1-X
- Molecular Formula C12H10N3O3P
- Molecular Weight (g/mol) 275.20
- Boiling Point (˚C/mmHg) 157° / 0.17
- Density (g/mL) 1.277
- Refractive Index @ 20˚C 1.5520
Additional Properties
Application
Reviewed along with other azides.1
Employed in preparation of macrocyclic lactams.2
Reagent for aziridation of olefins in presence of catalysts.3
Used as a reagent for a modified Curtius reaction.4
Fieser
F&F: Vol. 4, p 210; Vol. 5, p 280; Vol. 7, p 138; Vol. 8, p 211; Vol. 10, p 173, Vol. 16, p 160.
Reference
1. Swamy, K. C. K. et al. Chem. Rev. 2009, 109, 2551.
2. Qian, L. et al. Tetrahedron Lett. 1990, 31, 6469.
3. Ikeda, L. I. et al. Synthesis 1980, 650.
4. Shiiori, T.; Ninomiya, K.; Yamada, S. J. Am. Chem. Soc. 1972, 94, 6203.
Safety
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