TRIMETHYLCHLOROGERMANE

Product Code: GET8500
CAS No: 1529-47-1
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1529-47-1
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Price
 
5 g
$203.00
25 g
$806.00

Product data and descriptions listed are typical values, not intended to be used as specification.

  • Einecs Number

    216-214-4
  • HMIS

    3-4-1-X
  • Molecular Formula

    C3H9ClGe
  • Molecular Weight (g/mol)

    153.15
  • Purity (%)

    97%
  • TSCA

    No
  • Boiling Point (˚C/mmHg)

    102°
  • Density (g/mL)

    1.249
  • Flash Point (˚C)

    1 °C
  • Melting Point (˚C)

    -14°
  • Refractive Index @ 20˚C

    1.4337

Additional Properties

  • Hydrolytic Sensitivity

    7: reacts slowly with moisture/water

    • Application

    Forms germanium enolates which react under controlled conditions to give syn or anti aldols.1
    Reagent for regioselective synthesis of ?- or ?-aminoacids from masked dienolates.2,3
    In combination with HSiCl3 forms strained silicon epitaxial films.4

    Reference

    1. Yamamoto, Y. et al. F&F Vol. 14, p 329; J. Chem. Soc., Chem. Comm. 1988, 802.
    2. Yamamoto, Y. et al. Tetrahedron Lett. 1989, 30, 3445.
    3. Yamamoto, Y. et al. J. Org. Chem. 1990, 55, 3118.
    4. Woelk, E. et al. Semiconductor Int'l. 2006, 4, 39.

    Safety

  • Packaging Under

    Nitrogen