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TRIMETHYLCHLOROGERMANE
Boiling Point: 102°
EINECS Number: 216-214-4
Melting Point: -14°
Molecular Weight: 153.15
Specific Gravity: 1.249
Flashpoint: 1°C (34°F)
HMIS Key: 3-4-1-X
Hydrolytic Sensitivity: 7: reacts slowly with moisture/water
Formula: C3H9ClGe
Refractive Index: 1.4337
Application: Forms germanium enolates which react under controlled conditions to give syn or anti aldols.1
Reagent for regioselective synthesis of ?- or ?-aminoacids from masked dienolates.2,3
In combination with HSiCl3 forms strained silicon epitaxial films.4
Reference: 1. Yamamoto, Y. et al. F&F Vol. 14, p 329; J. Chem. Soc., Chem. Comm. 1988, 802.
2. Yamamoto, Y. et al. Tetrahedron Lett. 1989, 30, 3445.
3. Yamamoto, Y. et al. J. Org. Chem. 1990, 55, 3118.
4. Woelk, E. et al. Semiconductor Int'l. 2006, 4, 39.
Additional Properties: Dipole moment: 2.89 debye
Gases
Intermediate