BIS[BIS(TRIMETHYLSILYL)AMINO]GERMANIUM(II)

Product Code: GEB1025
CAS No: 55290-25-0
SDS Sheets: EU | US
Pack Size
Quantity
Price
 
2.5 g
$168.00
10 g
$542.00

Product data and descriptions listed are typical values, not intended to be used as specification.

  • Synonyms

    GERMANIUM(II) BIS(HEXAMETHYLDISILAZIDE)
  • HMIS

    2-1-1-X
  • Molecular Formula

    C12H36GeN2Si4
  • Molecular Weight (g/mol)

    393.36
  • TSCA

    No
  • Boiling Point (˚C/mmHg)

    60/0.4
  • Melting Point (˚C)

    32-3°

Additional Properties

  • Hydrolytic Sensitivity

    8: reacts rapidly with moisture, water, protic solvents
  • Application

    Intermediate for germazene.1
    Forms poly(germanium enolates) by reaction with ?,?-unsaturated ketones.2
    Reacts with carbon dioxide to form silylated isocyanates and carbodiimides.3
    Forms 3-coordinate complexes with (Et3P)2Ptacac that reversibly bind CO2, H2.4

    Reference

    1. Chen, H. et al. Inorg. Chem. 1991, 30, 3390.
    2. Kobayashi, S. et al. J. Am. Chem. Soc. 1992, 114, 4929.
    3. Sita, L. et al. J. Am. Chem. Soc. 1996, 118, 10912.
    4. Litz, K. et al. Organometallics 1995, 14, 5008.

    Safety

  • Packaging Under

    Nitrogen