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BIS[BIS(TRIMETHYLSILYL)AMINO]GERMANIUM(II)
Boiling Point: 60° / 0.4
Melting Point: 32-3°
Molecular Weight: 393.36
Alternative Name: GERMANIUM(II) BIS(HEXAMETHYLDISILAZIDE)
HMIS Key: 2-1-1-X
Hydrolytic Sensitivity: 8: reacts rapidly with moisture, water, protic solvents
Formula: C12H36GeN2Si4
Application: Intermediate for germazene.1
Forms poly(germanium enolates) by reaction with ?,?-unsaturated ketones.2
Reacts with carbon dioxide to form silylated isocyanates and carbodiimides.3
Forms 3-coordinate complexes with (Et3P)2Ptacac that reversibly bind CO2, H2.4
Reference: 1. Chen, H. et al. Inorg. Chem. 1991, 30, 3390.
2. Kobayashi, S. et al. J. Am. Chem. Soc. 1992, 114, 4929.
3. Sita, L. et al. J. Am. Chem. Soc. 1996, 118, 10912.
4. Litz, K. et al. Organometallics 1995, 14, 5008.
Additional Properties: Color: orange-yellow
Germanium Compounds
Silanes