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VANADIUM TRIISOPROPOXIDE OXIDE
EINECS Number: 226-997-4
Specific Gravity: 1.029
Flashpoint: 58°C (136°F)
HMIS Key: 2-2-1-X
Hydrolytic Sensitivity: 8: reacts rapidly with moisture, water, protic solvents
Refractive Index: 1.481
Application: Catalyst for the polymerization of olefins.1
Highly reactive intermediate for sol-gels with potential applications for humidity sensors and electrochromic display devices.2
Forms durable thermochromic gels with 10% Ge(OEt)4.3
Forms clear vanadia-silica aerogels able to polymerize acetylenes.4
Forms sol-gel derived Au dispersed electrochromic coatings.5
Forms xerogel cathodes for lithium polyelectrolyte cells.6
Vanadium-silica sol-gels with controlled microporosity for catalysts prepared.7
Sol-gel reaction with ?,?-diamines followed by hydrothermal treatment yields nanotubes.8
Forms flexible electrodes on block polymer matrices.9
Reference: 1. Christman, D. J. Polym. Sci. A-1 1972, 10(2), 471.
2. Livage, J. et al. Prog. in Solid State Chem. 1988, 18, 259.
3. Hirashima, H. et al. J. Non-Cryst. Solids 1990, 121, 168.
4. Stiegman, A. et al. Chem. Mater. 1993, 5, 1591.
5. Nagase, K. J. Mater. Chem. 1984, 4, 1581.
6. Davies, A. et al. J. Mater. Chem. 1996, 6, 49.
7. Curran, M. et al. Chem. Mater. 1998, 10, 3156.
8. Curran, M. et al. Chem. Mater. 1999, 11, 1120.
9. Olivetti, E., et al. Chem. Mater. 2006, 18, 2828.