To search by structure, left click in the box below to display the chemdraw toolbar. Then, draw the chemical structure of interest in the box using the toolbar. When your structure is complete, click “Search by Name” or “Search by SMILES” to generate the product name or SMILES respectively. This feature will search within the Gelest product database for matching chemical names or SMILES. Note: In cases where Gelest uses alternate chemical names, it may be necessary to search for the product of interest by its CAS#.
All structures are computer generated. Please rely on the product data below for placing your order. If you see any errors in structures, please email customer service so that they can be addressed.
TITANIUM ISOPROPOXIDE
Boiling Point: 58° / 1
EINECS Number: 208-909-6
Melting Point: 15-19°
Molecular Weight: 284.25
Specific Gravity: 0.937
Flashpoint: 25°C (77°F)
HMIS Key: 2-3-1-X
Hydrolytic Sensitivity: 7: reacts slowly with moisture/water
Formula: C12H28O4Ti
Refractive Index: 1.4654
TSCA: TSCA
Application: Vapor phase pyrolysis gives oxide.1
Yields coatings of barium titanate in combination with Ba(OR)2.2
Utilized in spray pyrolysis synthesis of BaTiO3 and SrTiO3.3
Catalyst for rearrangement4 and cleavage5 of epoxy alcohols.
Catalyst for cyclization of ?-amino acids to lactams.6
In combination with lead alkyls yields PZT films by MOCVD.7
Review of reactions in combination with Grignard reagents and various organic substrates.8
In combination with triethylamine and trimethylchlorosilane extends aldehydes to two carbons to enals.9
Reference: 1. Nandi, M. et al. Inorg. Chem. 1990, 29, 3065.
2. Scuhoff, L. U.S. Patent 3,002,861, 1961.
3. Nonaka, S. et al. J. Mater. Res. 1991, 6, 1750.
4. Morgans, D. et al. J. Am. Chem. Soc. 1981, 103, 462.
5. Caron, M. et al. J. Org. Chem. 1985, 50, 1557.
6. Mader, M. et al. Tetrahedron Lett. 1988, 29, 3049.
7. Kwak, B. S. et al. Appl. Phys. Lett. 1988, 53, 1702.
8. Wolan, A.; Six, Y. Tetrahedron 2010, 66, 15.
9. Kagana, N. et al. Tetrahedron Lett. 2010, 51, 482.
Fieser: F&F: Vol. 6, p. 11; Vol. 10, p. 404; Vol. 11, p. 3724 Vol. 12, p. 19, 504; Vol. 13, p. 13; Vol. 14, p. 247, 311; Vol. 16, p. 339; Vol. 17, p. 347.
Additional Properties: Metal content: 16.6-16.9% TiMolecular complexity: 1.4?Hform: -377 kcal/mole?Hvap: 14.7 kcal/moleSoluble: heptane, isopropanolVapor pressure, 50°: 0.9 mmVapor pressure, 100°: 19 mm
Metal-Organics
Silanes