546-68-9

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TITANIUM ISOPROPOXIDE

Product Code: AKT872

Cas No: 546-68-9

17 kg
$510.00
2 kg
$94.00
100 g
$17.00
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ALD Material

Atomic layer deposition (ALD) is a chemically self-limiting deposition technique that is based on the sequential use of a gaseous chemical process. A thin film (as fine as -0.1 Å per cycle) results from repeating the deposition sequence as many times as needed to reach a certain thickness. The major characteristic of the films is the resulting conformality and the controlled deposition manner. Precursor selection is key in ALD processes, namely finding molecules which will have enough reactivity to produce the desired films yet are stable enough to be handled and safely delivered to the reaction chamber.

Titanium isopropoxide; Isopropyltitanate; Titanium tetra(2-propoxide); Tetraisopropyl titanate
  • Viscosity: 2 cSt
  • ΔHform: -377 kcal/mol
  • ΔHvap: 14.7 kcal/mol
  • Metal content: 16.6-16.9% Ti
  • Vapor pressure, 50 °C: 0.9 mm
  • Vapor pressure, 100 °C: 19 mm
  • Soluble: heptane, isopropanol
  • Molecular complexity: 1.4
  • Vapor phase pyrolysis gives oxide
  • Yields coatings of barium titanate in combination with Ba(OR)2
  • Utilized in spray pyrolysis synthesis of BaTiO3 and SrTiO3
  • Catalyst for rearrangement and cleavage of epoxy alcohols
  • Catalyst for cyclization of ω-amino acids to lactams
  • In combination with lead alkyls yields lead zirconate titanate (PZT) films by Metal-Organic Chemical Vapour Deposition (MOCVD)
  • In combination with triethylamine and trimethylchlorosilane extends aldehydes to two carbons to enals
  • Provides scratch-resistance for glass bottles by pyrolytic coating at 500 °C

    • EINECS Number: 208-909-6

    Specific Gravity: 0.937

    Flashpoint: 25°C (77°F)

    HMIS Key: 2-3-1-X

    Hydrolytic Sensitivity: 7: reacts slowly with moisture/water

    Formula: C12H28O4Ti

    TSCA: TSCA

    Refractive Index: 1.4654

    Application: Vapor phase pyrolysis gives oxide.1
    Yields coatings of barium titanate in combination with Ba(OR)2.2
    Utilized in spray pyrolysis synthesis of BaTiO3 and SrTiO3.3
    Catalyst for rearrangement4 and cleavage5 of epoxy alcohols.
    Catalyst for cyclization of ?-amino acids to lactams.6
    In combination with lead alkyls yields PZT films by MOCVD.7
    Review of reactions in combination with Grignard reagents and various organic substrates.8
    In combination with triethylamine and trimethylchlorosilane extends aldehydes to two carbons to enals.9

    Reference: 1. Nandi, M. et al. Inorg. Chem. 1990, 29, 3065.
    2. Scuhoff, L. U.S. Patent 3,002,861, 1961.
    3. Nonaka, S. et al. J. Mater. Res. 1991, 6, 1750.
    4. Morgans, D. et al. J. Am. Chem. Soc. 1981, 103, 462.
    5. Caron, M. et al. J. Org. Chem. 1985, 50, 1557.
    6. Mader, M. et al. Tetrahedron Lett. 1988, 29, 3049.
    7. Kwak, B. S. et al. Appl. Phys. Lett. 1988, 53, 1702.
    8. Wolan, A.; Six, Y. Tetrahedron 2010, 66, 15.
    9. Kagana, N. et al. Tetrahedron Lett. 2010, 51, 482.

    Fieser: F&F: Vol. 6, p. 11; Vol. 10, p. 404; Vol. 11, p. 3724 Vol. 12, p. 19, 504; Vol. 13, p. 13; Vol. 14, p. 247, 311; Vol. 16, p. 339; Vol. 17, p. 347.

    Additional Properties: 16.6-16.9% Ti
    1.4
    ?Hform: -377 kcal/mole
    ?Hvap: 14.7 kcal/mole
    Heptane, Isopropanol
    Vapor pressure, 100°: 19 mm