TITANIUM CHLORIDE TRIISOPROPOXIDE, 95%

Product Code: AKT851
CAS No: 20717-86-6
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20717-86-6
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100 g
$51.00
500 g
$198.00
4 kg
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18 kg
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200 kg
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Product data and descriptions listed are typical values, not intended to be used as specification.

  • HMIS

    3-3-1-X
  • Molecular Formula

    C9H21ClO3Ti
  • Molecular Weight (g/mol)

    260.62
  • Purity (%)

    95%
  • TSCA

    Yes
  • Boiling Point (˚C/mmHg)

    63-6° / 0.1
  • Density (g/mL)

    1.091
  • Flash Point (˚C)

    22 °C
  • Melting Point (˚C)

    34-6°

Application

Reagent for conversion of carbanions and enolates to titanates with stereoselectivity.1,2
Provides benzyltriisopropoxytitanium compounds suitable for cross-linking to form diarylmethanes or aryl-heteroarylmethanes.3
Employed in the enantioselective arylation of aldehydes.4

Fieser

F&F: Vol. 11, p 375; Vol. 14, p 87.

Reference

1. Seigel, C.; Thornton, E. R. Tetrahedron Lett. 1986, 27, 457.
2. Nerz-Stonies, M.; Thornton, E. R. Tetrahedron Lett. 1986, 27, 897.
3. Chang, S-T. et al. Tetrahedron, 2012, 68, 3956.
4. Uenishi, A. et al. Chem. Eur. J. 2013, 19, 4896.

Safety

  • Packaging Under

    Nitrogen