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- HMIS 3-3-1-X
- Molecular Formula C9H21ClO3Ti
- Molecular Weight (g/mol) 260.62
- Purity (%) 95%
- TSCA Yes
- Boiling Point (˚C/mmHg) 63-6° / 0.1
- Density (g/mL) 1.091
- Flash Point (˚C) 22°C (72°F)
- Melting Point (˚C) 34-6°
Application
Reagent for conversion of carbanions and enolates to titanates with stereoselectivity.1,2
Provides benzyltriisopropoxytitanium compounds suitable for cross-linking to form diarylmethanes or aryl-heteroarylmethanes.3
Employed in the enantioselective arylation of aldehydes.4
Fieser
F&F: Vol. 11, p 375; Vol. 14, p 87.
Reference
1. Seigel, C.; Thornton, E. R. Tetrahedron Lett. 1986, 27, 457.
2. Nerz-Stonies, M.; Thornton, E. R. Tetrahedron Lett. 1986, 27, 897.
3. Chang, S-T. et al. Tetrahedron, 2012, 68, 3956.
4. Uenishi, A. et al. Chem. Eur. J. 2013, 19, 4896.
Safety
