TITANIUM CHLORIDE TRIISOPROPOXIDE, 95%

Product Code: AKT851
CAS No: 20717-86-6
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Quantity
Price
 
100 g
$51.00
500 g
$198.00
4 kg
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18 kg
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200 kg
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Prices listed are EXW price (Morrisville, PA US) in USD. Prices vary depending on currency and Incoterms.

Product data and descriptions listed are typical values, not intended to be used as specification.

  • HMIS

    3-3-1-X
  • Molecular Formula

    C9H21ClO3Ti
  • Molecular Weight (g/mol)

    260.62
  • Purity (%)

    95%
  • TSCA

    Yes
  • Boiling Point (˚C/mmHg)

    63-66/0.1
  • Density (g/mL)

    1.091
  • Flash Point (˚C)

    22 °C
  • Melting Point (˚C)

    34-6°

Application

Reagent for conversion of carbanions and enolates to titanates with stereoselectivity.1,2
Provides benzyltriisopropoxytitanium compounds suitable for cross-linking to form diarylmethanes or aryl-heteroarylmethanes.3
Employed in the enantioselective arylation of aldehydes.4

Fieser

F&F: Vol. 11, p 375; Vol. 14, p 87.

Reference

1. Seigel, C.; Thornton, E. R. Tetrahedron Lett. 1986, 27, 457.
2. Nerz-Stonies, M.; Thornton, E. R. Tetrahedron Lett. 1986, 27, 897.
3. Chang, S-T. et al. Tetrahedron, 2012, 68, 3956.
4. Uenishi, A. et al. Chem. Eur. J. 2013, 19, 4896.

Safety

  • Packaging Under

    Nitrogen