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TITANIUM CHLORIDE TRIISOPROPOXIDE, 95%
Boiling Point: 63-6° / 0.1
Melting Point: 34-6°
Molecular Weight: 260.62
Specific Gravity: 1.091
Flashpoint: 22°C (72°F)
HMIS Key: 3-3-1-X
Hydrolytic Sensitivity: TSCA
Application: Reagent for conversion of carbanions and enolates to titanates with stereoselectivity.1,2
Provides benzyltriisopropoxytitanium compounds suitable for cross-linking to form diarylmethanes or aryl-heteroarylmethanes.3
Employed in the enantioselective arylation of aldehydes.4
Reference: 1. Seigel, C.; Thornton, E. R. Tetrahedron Lett. 1986, 27, 457.
2. Nerz-Stonies, M.; Thornton, E. R. Tetrahedron Lett. 1986, 27, 897.
3. Chang, S-T. et al. Tetrahedron, 2012, 68, 3956.
4. Uenishi, A. et al. Chem. Eur. J. 2013, 19, 4896.
Fieser: F&F: Vol. 11, p 375; Vol. 14, p 87.