COMMERCIAL
3264-82-2

All structures are computer generated. Please rely on the product data below for placing your order. If you see any errors in structures, please email customer service so that they can be addressed.

NICKEL(II) 2,4-PENTANEDIONATE

Product Code: AKN580

Cas No: 3264-82-2

R&D quantities:

100 g
$121.00
25 g
$38.00

EINECS Number: 221-875-7

Melting Point: 208° dec

Molecular Weight: 256.91

Specific Gravity: 1.455

HMIS Key: 3-1-0-X

Hydrolytic Sensitivity: 0: forms stable aqueous solutions

Formula: C10H14NiO4

Refractive Index: 1.57-1.64

TSCA: TSCA

Application: Catalyzes conjugate addition of alkynyl aluminums to enones.1
Catalyzes coupling of Grignard reagents to give biaryls.2
Catalyzes Grignard additions to silyl enol ethers forming alkenes.3
Thermochromic effect in non-coordinating solvents at 200°C.4
UV stabilizer for polyphenylene sulfide.5
Catalyzes coupling of dialkylzincs with alkyl iodides.6
Intermediate for Ni nanoparticles by reduction with NaBH4.7
Forms Ni3C nanocrystals by thermolysis in oleylamine.8

Reference: 1. Hansen, R. T. et al. J. Am. Chem. Soc. 1978, 100, 2244.
2. Clough, R. L. J. Org. Chem. 1976, 41, 2252.
3. Hayashi, T. et al. Tetrahedron Lett. 1980, 3915.
4. Cotton, F. et al. J. Am. Chem. Soc. 1961, 83, 2818.
5. Stahlke, K. Chem. Abstr. 114, 144761u; Eur. Patent Application 326,888, 1989.
6. Giovannini, G. R. et al. J. Org. Chem. 1999, 64, 3544.
7. Green, M. et al. J. Chem. Soc., Chem. Commun. 2001, 1912.
8. Goto, Y. et al. Chem. Mater. 2008, 20, 4156.

Additional Properties: Solubility, methoxyethoxyethanol: 70 g/l
Solubility, toluene: 85 g/l
Solubility, water: 11.0 g/l
UV max: 265-298 nm
?Hsub: 16.5 kcal/mole
Color: green - turns turquoise on absorption of 3 moles H2O
Solubility, ethanol: 27 g/l
Metal content: 22.5-23.6% Ni
Trimeric compound
Vapor pressure, 145°: 0.01 mm