Gerald L. Larson

G. Larson, “Key Organosilane Reductions”, Specialty Chemicals Magazine, September 2008, 28, 54.

B. Arkles, G. L. Larson, “Silicon Compounds: Silanes & Silicones” Gelest Catalog, Gelest, Inc. 2008.

G. L. Larson, “1-Aza-2,5-disila-2,2,5,5-tetramethylcyclopentane” in e-EROS, John Wiley and Sons 2008.

G. L. Larson, “Vinyltrimethylsilane” in e-EROS, John Wiley and Sons 2007.

G. L. Larson, J. L. Fry, “Ionic and Organometallic-Catalyzed Organosilane Reductions”, in Organic Reactions S. E. Denmark, Ed. Volume 71, John Wiley and sons, pp 1-771, 2008.

G. L. Larson, “Silicon-Based Reducing Agents”. Version 2.0, Gelest, Inc. 2008.

G. L. Larson, “Silicon-Based Blocking Agents”,Version 3.0 Gelest, Inc. 2006.

B. Arkles, Y. Pan, G. L. Larson, D. H. Berry, “Cyclic Azasilanes: Volatile Coupling Agents for Nanotechnology”, Silanes and Other Coupling Agents, Vol. 3, Ed. K. L. Mittal, pp 179-191, 2004

Ricci, G. C. Seconi, R. Curci, G. L. Larson, "Organosilyl Peroxides", in Advances in Silicon Chemistry, Vol 3, G. L. Larson, ed. JAI Press, Greenwich, CT USA.

G. L Larson, "The Chemistry of a-Silyl Carbonyl Compounds" in Advances in Silicon Chemistry, Vol 3, G. L. Larson ed. JAI Press, Greenwich, CT. USA.

G. L. Larson “Silicon-Based Cross-Coupling Reactions”, 2008, Gelest, Inc.

R. Chawla, G. L. Larson, “Preparation of 1,1,3,3-Tetraisopropyl-1,3-dichlorodisiloxane and Triispropylchlorosilane”, Synthetic Commun. 29, 3499, 1999.

G. L. Larson, R. R. Chawla, C. S. Subramaniam, T. V. John, "A Commercially Viable Synthesis of Cyanotrimethylsilane", Org. Proc. Res. Dev., 1, 90 (1997).

G. L. Larson, "Ethyl a-(Methyldiphenylsilyl)acetate", Encyclopedia of Reagents in Organic Synthesis, L. A. Paquette, Ed., in press.

G. L. Larson, "Ethyl a-(Methyldiphenylsilyl)propionate", Encyclopedia of Reagents in Organic Synthesis, L. A. Paquette, Ed., in press.

G. L. Larson, "N,N-Dimethyl-2-(trimethylsilyl)acetamide", Encyclopedia of Reagents in Organic Synthesis, L. A. Paquette, Ed., in press.

G. L. Larson, "Trimethylsilylacetone", Encyclopedia of Reagents in Organic Synthesis, L. A. Paquette, Ed., in press.

G. L. Larson, "Methyldiphenylchlorosilane", Encyclopedia of Reagents in Organic Synthesis, L. A. Paquette, Ed., in press.

G. L. Larson, "Trimethylsilyl-t-butylamine", Encyclopedia of Reagents in Organic Synthesis, L. A. Paquette, Ed., in press.

T. J. Delord, F. R. Fronczek, R. M. Betancourt de Perez, G. L. Larson, "Structure of an a-(Methyldiphenylsilyl)-g-lactone", Acta Cryst., C49, 1799 (1993).

J. A. Prieto, M. T. Pallares, G. L. Larson, "Preparation and Reactions of Ethyl 1-(Diphenyl-methylsilyl)cyclopropane Carboxylate", Synlett., 199 (1993).

G. L. Larson, F. C. Cartledge, R. Nunez, R. J. Unwalla, R. Klesse, L. Del Valle, "The Preparation of (a,a-Dichlorobenzyl)silanes and (a-Halobenzyl)silanes" Organometallics, 11, 859 (1992).

G. L. Larson, Editor "Advances in Silicon Chemistry" Volume 1, 1992.

G. L. Larson, "Silicon The Silicon-Carbon Bond: Annual Survey for the Year 1989, J. Organometal. Chem., 1991.

G. L. Larson, "Trimethylsilyldiazomethane", Silicon Compounds, Register and Review, Hüls America, Inc., 1991.

G. L. Larson, "Trimethylsilylnitrile", Silicon Compounds, Register and Review, Hüls America, Inc., 1991.

G. L. Larson, "Trimethylsilyl Iodide", Silicon Compounds, Register and Review, Hüls America, Inc., 1991.

G. L. Larson, "Silicon The Silicon-Carbon Bond: Annual Survey for the Year 1988, J. Organometal. Chem., 1991.

F. R. Fronczek, G. L. Larson and J. Suarez, "Racemic tert-Butyl-(1-Naphthylphenylmethyl-silyl) Acetate", Acta Cryst., C46, 2480 (1990).

G. L. Larson, "a-Silyl Carbonyl Compounds" Pure and Applied Chemistry, Pure and Applied Chemistry, 62, 2021 (1990).

G. L. Larson, J. A. Soderquist, M. Rivera Claudio, "Preparation of b-Silyl-a,b-Unsaturated Esters and 3-Silyl Allyl Alcohols", Synthetic Commun., 20, 1095-1104 (1990).

G. L. Larson, "Silicon-The Silicon-Carbon Bond: Annual Survey for the Year 1987", J. Organometal. Chem., 374, 1 (1989).

G. L. Larson, "Silicon The Silicon-Carbon Bond: Annual Survey for the Year 1986, J. Organometal. Chem., 360, 39 (1989).

G. L. Larson, J. A. Prieto, P. Gonzalez, "A Synthesis of Fused Butenolides", Synthetic Commun., 19, 2779 (1989).

J. A. Prieto, G. L. Larson, P. Gonzalez, "The Stereochemistry of the Reaction of a-Silyl Lithium Reagents with Cyclic Tert-Butyldimethylsilyl Acyloins", Synthetic Commun. 19, 2773 (1989).

G. L. Larson, J. A. Prieto, L. del Valle, "The Reaction of a,a-Dichloro-benzyltrimethylsilane with Some Aldehydes and Ketones", Synth. Commun., 19, 1405 (1989).

G. L. Larson, "Recent Synthetic Applications of Organosilanes" in The Chemistry of Organic Silicon Compounds S. Patai and Z. Rappoport, eds. John Wiley & Sons, Ltd. 1989, Chapter 11 pp 764-808.

J. A. Prieto, G. L. Larson, R. Berrios, "A Regio- and Stereoselective Synthesis of Enol (Methyldiphenylsilyl) Ethers", Tetrahedron Lett., 30, 283 (1989).

G. L. Larson, J. A. Prieto, E. Ortiz, "The Preparation and Chemistry of (R)-(1-Naphthyl)-phenylmethylsilylmethyllithium: Stereochemistry at Silicon in the Elimination of b-Hydroxysilanes", Tetrahedron, 44, 3781 (1988).

C. L. Barnes, G. L. Larson., A. Santiago, J. Rios Steiner, "Ethyl 3-(2-Methyl-1,3-dioxolan-2-yl)-2-(methyldiphenylsilyl)propionate", Acta Cryst. C44, 1323 (1988).

C. L. Barnes, G. L. Larson, Y. -S. Lee, "Trans 1,1,2,5-tetraphenyl-1-silacyclopentane", Acta Cryst., C44, 1148 (1988).

G. L. Larson, C. L. Barnes, S. B. Sandoval, "Trans -1,2,5-triphenyl-1-silacyclopentane", Acta Cryst., C44, 1147 (1988).

J. A. Prieto, G. L. Larson, R. Berrios, A. Santiago, "A Silicon Facilitated Preparation of 1,3 Dienes", Synthetic Commun., 18, 1385 (1988).

G. L. Larson, "Organosilanes in Organic Synthesis" VIIIth International Symposium on Organosilicon Chemistry, St. Louis, MO 1987.

G. L. Larson (with B. Arkles and R. Anderson) editor of "Silicon Compounds, Register and Review", Petrarch Systems, 1987.

W. R. Peterson, R. Anderson, G. L. Larson, "Silane Blocking Agents", Silicon Compounds, Register and Review, Petrarch Systems, 1987.

G. L. Larson, "An Introduction to Organosilicon Chemistry", Silicon Compounds, Register and Review, Petrarch Systems, 1987.

J. A. Prieto, J. Suarez and G. L. Larson, "The Regioselectivity of Deprotonation of Unsymmetrical Ketones with Lithium Tert-Butyltrilakylsilyl Amides", Synthetic Commun., 18, 253 (1988).

E. Torres, G. L. Larson and G. J. McGarvey, "An Asymmetric Hydrogen Equivalent: Use of the 1-Napthylphenylmethylsilyl Group in the Synthesis of Optically Active Allyl Alcohols and 1-Phenyl-1,2-Butadiene", Tetrahedron Lett., 29, 1355 (1988).

G. L. Larson, V. Cruz de Maldonado, L.M. Fuentes and L.E. Torres, "The Methyldiphenyl-silylation of Ester and Lactone Enolates", J. Org. Chem., 53, 633 (1988).

G. L. Larson, I. Montes de Lopez-Cepero and L. Rodriguez, "a-Diphenyl-methylsilylation of Ester Enolates: 2-Methyl-2-Undecene from Ethyl Decanoate", Organic Synthesis, 67, 125 (1988).

G. L. Larson, R. Klesse and F.K. Cartledge, "Thermal Rearrangement of (S,S)-1-Naphthyl-phenylmethyl(1-chloroethyl)silane and (S)-(1-Chloro-ethyl)phenyldimethylsilane", Organometallics, 6, 2250, 1987.

M. A. de Jesus, J. A. Prieto, L. del Valle, G. L. Larson, "Trichloromethyl-anion Chemistry from Trimethylsilyl Trichloroacetate", Synthetic Commun., 17, 1047 (1987).

Y. -S. Lee, L. del Valle, G. L. Larson, "A Ready Preparation of 2-(2-Iodoethyl)-1,3-dioxane: A Facile three-Carbon Extension of Grignard Reagents", Synthetic Commun., 17, 385 (1987).

G. L. Larson, "Silicon-The Silicon-Carbon Bond-Annual Survey for the year 1985", J. Organometal. Chem. 337, 195-430 (1987).

V. Cruz de Maldonado and G. L. Larson, "The (Methyldiphenylsilylation) of Carboxylic Acid Dianions", Synthetic Commun., 16, 1347 (1986).

L. E. Torres and G. L. Larson, "The Palladium (II)Acetate-Mediated 6-Endo-Trig Cyclization of 1,1-Dialkyl-2-Silyloxy-1,5-Dienes", Tetrahedron Lett., 27, 2223 (1986).

G. L. Larson, E. Torres, C. Burgos Morales, G. J. McGarvey, "The Preparation and Reactions of (E) a-Lithio-a-(Methyldiphenylsilyl) Alkenes", Organometallics, 5, 2274 (1986).
R. M. Betancourt de Perez, G. L. Larson, C. L. Barnes and M. J. Heeg, "A Synthesis of 4-Oxo Carboxylic Acids, 4-Oxo Aldehydes, and 1,4-Diketones from g-Lactones", J. Org. Chem., 51, 2039 (1986).

G. L. Larson, "Silicon-The Silicon-Carbon Bond-Annual Survey for the year 1984, J. Organomet. Chem. (Book-Chapter), 313, 141 (1986).

G. L. Larson, A. Santiago and I. Montes de Lopez-Cepero, "A Synthesis of 2,2-Ethylenedioxy 6-Ketones", Synthetic Commun. 16, 697 (1986).

G. L. Larson, A. Santiago and I. Montes de Lopez-Cepero, "A Synthesis of 2,2-Ethylenedioxy 5-Ketones", Synthetic Commun., 16, 705 (1986).

G. L. Larson, D. Hernandez, I. Montes de Lopez-Cepero and L. E. Torres, "The Reaction of Alpha (Diphenylmethylsilyl) Esters with Grignard Reagents: A Synthesis of b-Ketosilanes and Ketones. The Synthesis of the Douglas Tussock Fir Moth Pheromone", J. Org. Chem., 50, 5260 (1985).

G. L. Larson and R. M. Betancourt de Perez, "A Two-Step Preparation of a-Ylidene Gamma Lactones From g-Lactones: A Synthesis of Racemic Ancepsenolide", J. Org. Chem., 50, 5257 (1985).

G. L. Larson and R. Klesse, "An Improved Synthesis of the Ethylene Acetal of 3-Iodopropanal and The Ethylene Ketal of 4-Iodo-2-butanone", J. Org. Chem., 50, 3627 (1985).

G. L. Larson and E. Torres, "Asymmetric Induction by Chiral Silicon Groups", J. Organometal. Chem., 293, 19, (1985).

G. L. Larson, "Silicon-The Silicon-Carbon Bond-Annual Survey for 1983", J. Organometal. Chem. Libr., 17, pp 1-162 J. Oliver Ed., Elsevier Publishing Co., New York, (1985) (Book-Chapter).

G. L. Larson, "Silicon-The Silicon-Carbon Bond-Annual Survey for 1982", J. Organometal. Chem., 274, 29 (1984) (Book-Chapter).

G. L. Larson, "a-Silyl Carbonyl Compounds: Synthesis and Characterization", "Silicon Compounds: Register and Review", Petrarch Systems, Inc. Bristol, PA. 22 (1984) Review.

G. L. Larson, J. Organometallic Chem. Libr., 14, 267 J. Oliver and R. B. King Eds., Elsevier Scientific Publishing Co., New York, (Book-Chapter).

G. L. Larson and D. Hernandez, "The Synthesis of Tri- and Tetra-Substituted Olefins From Alpha Silyl Esters", J. Org. Chem., 49, 4285 (1984).

G. L. Larson, C. Fernandez de Kaifer, R. Seda, L. E. Torres and J. R. Ramirez, "A Stereo-selective, Two-Step Preparation of a-Alkyl, a, b-Unsaturated Esters", J. Org. Chem., 49, 3385 (1984).

G. L. Larson, I. Montes de Lopez-Cepero and L. E. Torres, "An Efficient Synthesis of Beta Ketosilanes" Tetrahedron Lett., 25, 1673 (1984).

G. L. Larson and V. Cruz de Maldonado, "A Silicon Mediated Conversion of Esters to Terminal Olefins and Specifically Deuterated Olefins", Synthetic Commun., 13, 1163 (1983).

G. L. Larson, F. Quiroz and J. Suarez, "Studies on the Stereoselectivity of the Preparation of a, b-Unsaturated Esters from a-Lithio a-Silyl Esters", Synthetic Commun., 13, 833 (1983).

G. L. Larson, J. Organometallic Chem. Libr., 13, 387 J. Oliver and R. B. King, Eds., Elsevier Scientific Publishing Co., New York 1983. (Book-Chapter)

G. L. Larson, S. Sandoval, F. Cartledge and F. R. Fronczek, "a-Haloethylsilanes Optically Active at Carbon and at Silicon: Synthesis and Absolute Configuration", Organometallics, 2, 810 (1983).

G. L. Larson and J. A. Prieto, "Entries into Prostanoid Models via the Hydroboration of Enol Silyl Ethers", Tetrahedron, 39, 855 (1983).

G. L. Larson and C. Cadiz, "Attempted Generation of Halocarbenes: Protodesilylation of Dihalomethylsilanes", J. Organometal. Chem. 232, 113-116 (1982).

G. L. Larson and M. Ortiz, "The Reaction of Sulfonyl Azides With Organoboranes", Synthetic Commun., 12, 43 (1982).

G. L. Larson and D. Hernandez, "Facile Synthesis of Symmetrical 1,1-Disubstituted Ethylenes", Tetrahedron Lett., 23, 1035, (1982).

L. M. Fuentes and G. L. Larson, "A Facile Synthesis of 4-oxo Carboxylic Acids From g-Butyrolactone", Tetrahedron Lett., 23, 271 (1982).

L. del Valle, S. Sandoval and G. L. Larson, "The Preparation of a, a-Dichloromethylsilanes Under Phase Transfer Conditions", J. Organomet. Chem., 215, C45 (1981).

G. L. Larson, M. Ortiz, M. Rodriguez de Roca, "The Reaction of Tri-methylsilyl Esters with Metal Hydride Reducing Agents. Protection of Carboxylic Acids as Their Trimethylsilyl Esters During Hydroboration", Synthetic. Commun., 11, 583 (1981).

G. L. Larson, J. A. Prieto and A. Hernandez, "Thermodynamic and Kinetic Control in the Reaction of Carboethoxymethylenetriphenylphosphorane and Ethyl Lithiotrimethylsilyl-acetate with 2-(tert-Butyldimethylsilyloxy)cycloalkanones", Tetrahedron Lett., 22, 1575 (1981).

G. L. Larson and L. M. Fuentes, "The C-Silylation of Lithium Ester Enolates", J. Am. Chem. Soc., 103, 2418 (1981).

G. L. Larson and L. del Valle, "The Reaction of Silanes with Chloroform Under Phase Transfer Conditions: An Unfortunate, Convenient Preparation of Disiloxanes" Syn. React. Inorg. Metal. Org. Chem., 11, 173 (1981).

A. Oliva and G. L. Larson, "Sintesis y Propiedades Espectrales de 1-(Arildimetilsilil)-2 propanonas y 2-(Arildimetilsiloxi)propenos", Rev. Latinoamer. Quim., 11, 143 (1980).

O. Rosario, S. Sandoval and G. L. Larson, "The Reaction of (Phenyldimethylsilyl)dichloro-methyllithium with Organoboranes. A Synthesis of a-Hydroxyorganosilanes and Ketones", Synthetic Commun., 10, 813 (1980).

J. A. Prieto and G. L. Larson, "Preparation of Trans-2-Acyl Cyclopentanols and Cyclo-hexanols", Synthetic Commun., 10, 675 (1980).

G. L. Larson, R. Arguelles, O. Rosario and S. Sandoval, "The Preparation of a-Hydroxy-organosilanes from Alpha Boryl Organosilyl Intermediates", J. Organomet. Chem., 198, 15 (1980).

R. S. -C. Tsai, G. L. Larson and A. Oliva, "A Mass Spectral Study of 1-(Aryldimethylsilyl)-2-Propanones and Their Isomeric 2-(Aryl- dimethylsilyl)-1-Propenes", Org. Mass Spec., 14, 364 (1979).

G. L. Larson and L. Fuentes, "A Reductive 1,2-Transposition of Acyclic Ketones", Synthetic Commun., 9, 841 (1979).

G. L. Larson and O. Rosario, "The Formation and Alkylation of (Tri-methylsilyl), (Phenyl-dimethylsilyl)- and (Diphenylmethylsilyl)- Dichloromethyllithium. Preparation of a, a-Dichloroalkylsilanes and ((Z)-1-Chloro-1-alkenyl)silanes", J. Organomet. Chem., 168, 13 (1979).

A. Oliva and G. L. Larson, "The Reaction of Chloromethylsilanes with Lithium Diisopropyl-amide", Rev. Latinoamer. Quim., 10, 54 (1979).

J. D. White and G. L. Larson, "The Reduction of Organic Substrates with Ytterbium-Ammonia Solution", J. Org. Chem., 43, 4555 (1978).

O. Rosario, A. Oliva and G. L. Larson, "A Synthesis of a-Hydroxysilanes", J. Organomet. Chem., 146, C8 (1978).

M. de Jesus, O. Rosario and G. L. Larson, "The Hydroboration-Oxidation of the Isomeric Trimethylsilylcyclohexenes and the Isomeric Trimethylsilylcyclopentenes", J. Organomet. Chem., 132, 301 (1977).

G. L. Larson, V. Nemeth and H. Valente, "A Convenient Synthesis of Arylsilanes from Chloro-benzenes", Syn. React. Inorg. Metalorg. Chem., 6, 21 (1976).

G. L. Larson and A. Hernandez, "The Stereochemistry of the b- Elimination of b-Trimethyl-siloxy Organoboranes", J. Organomet. Chem., 102, 123 (1975).

G. L. Larson, E. Hernandez, C. Alonso and I. Nieves, "A Synthesis of Olefins via Hydroboration of Cyclic Trimethylsilyl Enol Ethers", Tetrahedron Lett., 4005 (1975).

G. L. Larson and O. Rosario, "A Synthesis of a, b-Unsaturated Esters via Ethyl Lithio-trimethylsilylacetate", Rev. Latinoamer. Quim., 6, 16 (1975).

G. L. Larson and Y. V. Fernandez, "The Mechanism of the Thermal Rearrangement of Beta Ketosilanes", J. Organomet. Chem., 86, 193 (1975).

G. L. Larson, D. Hernandez and A. Hernandez, "The Hydroboration of Trimethylsilyl Enol Ethers", J. Organomet. Chem., 76, 9 (1974).

G. L. Larson and A. Hernandez, 'The Reaction of Trimethylsilyl Enol Ethers with 2-Mercapto-ethanol", Synthetic Commun., 4, 61 (1974).

G. L. Larson and A. Hernandez, "The Reaction of Trimethylsilyl Enol Ethers with Diols", J. Org. Chem., 38, 3935 (1973).

D. S. Matteson and G. L. Larson, "Tin and Lead Derivatives of tetrakis(dimethoxyboryl)-methane", J. Organomet. Chem., 57, 225 (1973).

R. T. Gray, J. Diekman, G. L. Larson, W. K. Musker and C. Djerassi, "Electron-Impact Induced Fragmentations and Rearrangements of Alkoxycyclohexanol Trimethylsilyl Ethers and Alkoxycyclohexyl Trimethylsilanes", Org. Mass Spec., 3, 973 (1970).

D. S. Matteson, R. B. Castle and G. L. Larson, "Tetrakis(acetoxymercury)methanes", J. Am. Chem. Soc., 92, 231 (1970).

D. S. Matteson and G. L. Larson, "Boron-Tin and Boron-Lead Tetrametallomethanes", J. Am. Chem. Soc., 91, 6541 (1969).

W. K. Musker and G. L. Larson, "The Stereochemistry of the Beta Elimination Reactions in Organosilanes", J. Am. Chem. Soc., 91, 514 (1969).

W. K. Musker and G. L. Larson, "Synthesis of the Cis and Trans Isomers of 2-Trimethylsilyl-cyclohexanol", Tetrahedron Lett., 3481 (1968).

W. K. Musker and G. L. Larson, "Intramolecular Interactions Involving Group IV Elements. Spectral Properties of 1-(Trimethylsilyl)-2-Propanone", J. Organomet. Chem., 6, 627 (1966).

©

Copyright 1991 - 2019 Gelest, Inc.