998-39-0

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TRI-n-BUTYLGERMANE, 99%

Product Code: GET8100

Cas No: 998-39-0

R&D quantities:

2.5 g
$142.00
10 g
$461.00

Interested in a Commercial Order?

Boiling Point: 123° / 20

Molecular Weight: 244.94

Alternative Name: TRIBUTYLGERMANIUM HYDRIDE

Specific Gravity: 0.916

Flashpoint: 78°C (172°F)

HMIS Key: 3-2-1-X

Formula: C12H28Ge

Purity: 99%

Refractive Index: 1.4508

Application: Effects free-radical reductive addition of alkyl halides to olefins with AIBN.1,2
Reduces benzylic chlorides 70 X faster than silyl hydrides.3
Initiates radical cyclization of polyenes.4

Reference: 1. Hershberger, J. Tetrahedron Lett. 1986, 26, 6289.
2. Pike, P. et al. Tetrahedron 1988, 44, 6295.
3. Mayr, H. et al. Angew. Chem., Int. Ed. Engl. 1992, 31, 1046.
4. Spino, C. et al. J. Org. Chem. 1999, 64, 5292.