Additional Properties
- Einecs Number 216-214-4
- HMIS 3-4-1-X
- Molecular Formula C3H9ClGe
- Molecular Weight (g/mol) 153.15
- Purity (%) 97%
- TSCA No
- Boiling Point (˚C/mmHg) 102
- Density (g/mL) 1.249
- Flash Point (˚C) 1 °C
- Melting Point (˚C) -14°
- Refractive Index @ 20˚C 1.4337
Application
Forms germanium enolates which react under controlled conditions to give syn or anti aldols.1
Reagent for regioselective synthesis of ?- or ?-aminoacids from masked dienolates.2,3
In combination with HSiCl3 forms strained silicon epitaxial films.4
Reference
1. Yamamoto, Y. et al. F&F Vol. 14, p 329; J. Chem. Soc., Chem. Comm. 1988, 802.
2. Yamamoto, Y. et al. Tetrahedron Lett. 1989, 30, 3445.
3. Yamamoto, Y. et al. J. Org. Chem. 1990, 55, 3118.
4. Woelk, E. et al. Semiconductor Int'l. 2006, 4, 39.
Safety