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TRI-n-BUTYLMETHOXYTIN
EINECS Number: 13-933-5
Specific Gravity: 1.169
Flashpoint: 98°C (208°F)
HMIS Key: 3-2-1-X
Hydrolytic Sensitivity: 7: reacts slowly with moisture/water
Formula: C13H30OSn
Refractive Index: 1.4745
Application: Cleaves ?-bromo-?-lactones to oxazolidines and homologs.1
Converts allylic hydroperoxides quantitatively to stannyl peroxides.2
Undergoes alcohol exchange, cyclization reactions.3
Reference: 1. Shibata, I. et al. J. Org. Chem. 1990, 55, 2487.
2. Haynes, R. et al. Chem. Comm. 1990, 6, 448.
3. Delmont, B. et al. J. Organomet. Chem. 1973, 47, 337.
Fieser: F&F: Vol. 16, p 351.
Tin Compounds
Tin Compounds