TETRA-p-TOLYLTIN

Product Code: SNT7894
CAS No: 6746-22-1
SDS Sheets: EU | US
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6746-22-1
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Pack Size
Quantity
Price
 
10 g
$110.00
50 g
$430.00

Product data and descriptions listed are typical values, not intended to be used as specification.

  • HMIS

    3-1-0-X
  • Molecular Formula

    C28H28Sn
  • Molecular Weight (g/mol)

    483.22
  • TSCA

    No
  • Boiling Point (˚C/mmHg)

    NA
  • Melting Point (˚C)

    236-7°

Additional Properties

  • Hydrolytic Sensitivity

    1: no significant reaction with aqueous systems

    • Safety

  • Packaging Under

    Nitrogen

    • Organotin Cross-Coupling Agent

    The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.

    Tetra-p-tolyltin; Tetrakis(p-tolyl)tin; Tetra-p-tolylstannane; Tetrakis(4-methylphenyl)tin; Tetrakis(4-methylphenyl)stannane

  • Stille Couppling p-tolylation reagent
  • Extensive review of silicon based cross-coupling agents: Denmark, S. E. et al. "Organic Reactions, Volume 75" Denmark, S. E. ed., John Wiley and Sons, 233, 2011

    • Metal-Organic Chemistry, Articles

    Introduction to Organotin Chemistry – Bossert

    Silicon Chemistry, Articles

    Silicon-Based Formation of Carbon-Carbon Bonds – Larson

    Hatanaka and Hiyama first reported the palladium-catalyzed, fluoride-promoted reaction of aryl, alkenyl, allyl, and ethynyltrimethylsilanes with aryl, vinil and allyl halides to form the respective cross-coupled products