2-PYRIDYLTRI-n-BUTYLTIN, 95%

Product Code: SNP6935
CAS No: 17997-47-6
SDS Sheets: EU | US
Pack Size
Quantity
Price
 
5 g
$179.00

Product data and descriptions listed are typical values, not intended to be used as specification.

  • HMIS

    3-1-1-X
  • Molecular Formula

    C17H31NSn
  • Molecular Weight (g/mol)

    368.14
  • Purity (%)

    95%
  • TSCA

    No
  • Boiling Point (˚C/mmHg)

    130-132/0.8
  • Density (g/mL)

    1.142
  • Flash Point (˚C)

    >110 °C

Additional Properties

  • Hydrolytic Sensitivity

    7: reacts slowly with moisture/water
  • Application

    Stille coupling with phenanthroline forms dipyridylphenanthroline ligand.1

    Reference

    1. Zong, R. et al. J. Am. Chem. Soc. 2004, 126, 10800.

    Safety

  • Packaging Under

    Nitrogen
  • Organotin Cross-Coupling Agent

    The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.

    2-Pyridyltri-n-butyltin; 2-Tri-n-butylstannylpyridine

  • Stille Coupling for formation of 2-pyridiyl derivatives
  • Contains tributyltin oxide
  • Stille coupling with phenanthroline forms dipyridylphenanthroline ligand
  • Extensive review of silicon based cross-coupling agents: Denmark, S. E. et al. "Organic Reactions, Volume 75" Denmark, S. E. ed., John Wiley and Sons, 233, 2011
  • Metal-Organic Chemistry, Articles

    Silicon Chemistry, Articles

    Silicon-Based Formation of Carbon-Carbon Bonds – Larson

    Hatanaka and Hiyama first reported the palladium-catalyzed, fluoride-promoted reaction of aryl, alkenyl, allyl, and ethynyltrimethylsilanes with aryl, vinil and allyl halides to form the respective cross-coupled products