Pack Size
Quantity
Price
 
5 g
$223.00

Product data and descriptions listed are typical values, not intended to be used as specification.

  • HMIS

    2-1-1-X
  • Molecular Formula

    C15H30Sn
  • Molecular Weight (g/mol)

    329.09
  • Purity (%)

    95%
  • TSCA

    No
  • Boiling Point (˚C/mmHg)

    277°
  • Density (g/mL)

    1.082
  • Flash Point (˚C)

    >110°C (>230°F)
  • Refractive Index @ 20˚C

    1.4835

Additional Properties

  • Hydrolytic Sensitivity

    4: no reaction with water under neutral conditions
  • Application

    Reacts with bicycloalkenylbis(phenyliodonium)triflates to yield bicyclic enediynes.1

    Reference

    1. Ryan, J. et al. J. Org. Chem. 1996, 61, 6162.

    Safety

  • Packaging Under

    Nitrogen
  • Organotin Cross-Coupling Agent

    The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.

    Propynyltri-n-butyltin; Tributylstannylpropyne; Tributyl(1-propynyl)tin

  • Reacts with bicycloalkenylbis(phenyliodonium)triflates to yield bicyclic enediynes
  • Transfer of propynyl group
  • Extensive review of silicon based cross-coupling agents: Denmark, S. E. et al. "Organic Reactions, Volume 75" Denmark, S. E. ed., John Wiley and Sons, 233, 2011
  • Metal-Organic Chemistry, Articles

    Silicon Chemistry, Articles

    Silicon-Based Formation of Carbon-Carbon Bonds – Larson

    Hatanaka and Hiyama first reported the palladium-catalyzed, fluoride-promoted reaction of aryl, alkenyl, allyl, and ethynyltrimethylsilanes with aryl, vinil and allyl halides to form the respective cross-coupled products