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Product Code: SNP6740

Cas No: 960-16-7

2.5 kg
50 g
10 g

Product data and descriptions listed are typical values, not intended to be used as specification.

Organotin Cross-Coupling Agent

The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.

Phenyltri-n-butyltin; Phenyltri-n-butylstannane
  • Transfers phenyl group to allylic acetates in Pd catalyzed reactions
  • Stille Coupling phenylation reagent
  • Transfers phenyl group to allylaic acetates in Pd-catalyzed reactions
  • Extensive review of silicon based cross-coupling agents: Denmark, S. E. et al. "Organic Reactions, Volume 75" Denmark, S. E. ed., John Wiley and Sons, 233, 2011
  • Specific Gravity: 1.125

    HMIS Key: 2-1-0-X

    Hydrolytic Sensitivity: 4: no reaction with water under neutral conditions

    Formula: C18H32Sn

    Refractive Index: 1.5155

    Application: Transfers phenyl group to allylic acetates in Pd catalyzed reactions.1,2

    Reference: 1. Stille, J. Angew. Chem., Int. Ed. Engl. 1986, 25, 508.
    2. Kosugi, M. Chem. Lett. 1987, 1237.