PHENYLTRI-n-BUTYLTIN

Product Code: SNP6740
CAS No: 960-16-7
SDS Sheets: EU | US
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Price
 
10 g
$123.00
50 g
$483.00
2.5 kg
$4,555.00

Product data and descriptions listed are typical values, not intended to be used as specification.

  • HMIS

    2-1-0-X
  • Molecular Formula

    C18H32Sn
  • Molecular Weight (g/mol)

    367.13
  • TSCA

    No
  • Boiling Point (˚C/mmHg)

    130/0.2
  • Density (g/mL)

    1.125
  • Refractive Index @ 20˚C

    1.5155

Additional Properties

  • Hydrolytic Sensitivity

    4: no reaction with water under neutral conditions

    • Application

    Transfers phenyl group to allylic acetates in Pd catalyzed reactions.1,2

    Reference

    1. Stille, J. Angew. Chem., Int. Ed. Engl. 1986, 25, 508.
    2. Kosugi, M. Chem. Lett. 1987, 1237.

    Safety

  • Packaging Under

    Nitrogen

    • Organotin Cross-Coupling Agent

    The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.

    Phenyltri-n-butyltin; Phenyltri-n-butylstannane

  • Transfers phenyl group to allylic acetates in Pd catalyzed reactions
  • Stille Coupling phenylation reagent
  • Transfers phenyl group to allylaic acetates in Pd-catalyzed reactions
  • Extensive review of silicon based cross-coupling agents: Denmark, S. E. et al. "Organic Reactions, Volume 75" Denmark, S. E. ed., John Wiley and Sons, 233, 2011

    • Metal-Organic Chemistry, Articles

    Introduction to Organotin Chemistry – Bossert

    Silicon Chemistry, Articles

    Silicon-Based Formation of Carbon-Carbon Bonds – Larson

    Hatanaka and Hiyama first reported the palladium-catalyzed, fluoride-promoted reaction of aryl, alkenyl, allyl, and ethynyltrimethylsilanes with aryl, vinil and allyl halides to form the respective cross-coupled products