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PHENYLTRI-n-BUTYLTIN
Product data and descriptions listed are typical values, not intended to be used as specification.
Organotin Cross-Coupling Agent
The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.
Phenyltri-n-butyltin; Phenyltri-n-butylstannane
Specific Gravity: 1.125
HMIS Key: 2-1-0-X
Hydrolytic Sensitivity: 4: no reaction with water under neutral conditions
Formula: C18H32Sn
Refractive Index: 1.5155
Application: Transfers phenyl group to allylic acetates in Pd catalyzed reactions.1,2
Reference: 1. Stille, J. Angew. Chem., Int. Ed. Engl. 1986, 25, 508.
2. Kosugi, M. Chem. Lett. 1987, 1237.
Tin Compounds
Tin Compounds
Silicon-Based Cross-Coupling Reagents
Enabling Synthetic Organic Transformations
Introduction to Organotin Chemistry – Bossert
Silicon-Based Formation of Carbon-Carbon Bonds – Larson